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信息承载Peptoids及其序列定向动态共价自组装的合成
JoVE Journal
Chemistry
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JoVE Journal Chemistry
Synthesis of Information-bearing Peptoids and their Sequence-directed Dynamic Covalent Self-assembly
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信息承载Peptoids及其序列定向动态共价自组装的合成

DOI:
10.3791/60442-v

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09:34 min

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February 06, 2020

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, ,
1Department of Chemical Engineering,University of Michigan, 2Department of Chemical Engineering,Monash University, 3Department of Materials Science and Engineering,Monash University

Chapters

  • 00:05Introduction
  • 01:20Solid-phase Submonomer Synthesis of Oligo(peptoids)
  • 06:01Sequence-selective Ladder Self-assembly Through Dissociation/Extraction/Annealing
  • 07:22Results: Analysis of Information-bearing Peptoids and Their Sequence-directed Dynamic Covalent Self-assembly
  • 08:31Conclusion

Summary

Automatic Translation

Automatic Translation

提出了一种方案，用于合成信息编码的肽寡聚物，以及将这些肽的序列定向自组装成分子阶梯，使用胺和醛作为动态共价反应物对和刘易斯酸性稀土金属三重膨胀作为多功能试剂。

Tags

PeptoidsDynamic Covalent Self-assemblySequence-directed AssemblyInformation-directed AssemblyLewis AcidKinetic TrappingCovalent Bond RearrangementFMOC Photolabile Solid Support ResinAutomated Peptide SynthesizerPrimary AmineBromoacetic AcidDICAcetic AnhydrideDMFNMP

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