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（2<em>ž</em>，4<em>电子</em>） - 通过电子缺陷烯烃与烯丙基乙酸酯的烯化反应制备二烯酰胺
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JoVE Journal Chemistry
Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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（2<em>ž</em>，4<em>电子</em>） - 通过电子缺陷烯烃与烯丙基乙酸酯的烯化反应制备二烯酰胺

English

Automatically Generated

7,230 Views

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06:46 min

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June 21, 2017

DOI:

10.3791/55766-v

DOI:
10.3791/55766-v

•

06:46 min
June 21, 2017

•

1 Views
, , , , ,
1College of Materials, Chemistry and Chemical Engineering,Hangzhou Normal University, 2Shijiazhuang Mechanized Infantry Academy

Summary

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这里描述了电子缺乏烯烃与乙酸烯丙酯的钌催化烯化反应。通过使用氨基羰基作为引导基团，该外部无氧化剂方案具有高效率和良好的立体选择性和开放的新的合成途径（ Z ， E ） - 丁二烯骨架。

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Cite this Article

Ding, L., Yu, C., Zhao, Z., Li, F., Zhang, J., Zhong, G. Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate. J. Vis. Exp. (124), e55766, doi:10.3791/55766 (2017).

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