Journal
/
Quimica
/
Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
JoVE Revista
Quimica
Se requiere una suscripción a JoVE para ver este contenido.  Inicie sesión o comience su prueba gratuita.
JoVE Revista Quimica
Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

DOI:
10.3791/55766-v

•

06:46 min

•

June 21, 2017

•

, , , , ,
1College of Materials, Chemistry and Chemical Engineering,Hangzhou Normal University, 2Shijiazhuang Mechanized Infantry Academy

Capítulos

  • 00:05Título
  • 01:00Preparation of Butadienes by the Olefination of Acrylamides with Allyl Acetate
  • 03:41Results: Preparation of 1,3-Butadiene via Ruthenium-catalyzed Olefination of Acrylamides with Allyl Acetate
  • 05:28Conclusion

Summary

Traducción Automática

Traducción Automática

The ruthenium-catalyzed olefination of electron-deficient alkenes with allyl acetate is described here. By using aminocarbonyl as a directing group, this external oxidant-free protocol has high efficiency and good stereo- and regioselectivity, opening a novel synthetic route to (Z,E)-butadiene skeletons.

Tags

OlefinationElectron-deficient AlkenesAllyl AcetateRuthenium CatalystZE-butadienesAcrylamideCross-couplingColumn ChromatographyNMR Spectroscopy

Article

Embed

Añadir a la lista de reproducción

Usage Statistics

Videos relacionados

Formation of Ordered Biomolecular Structures by the Self-assembly of Short Peptides

Facile and Efficient Preparation of Tri-component Fluorescent Glycopolymers via RAFT-controlled Polymerization

Facile Preparation of Internally Self-assembled Lipid Particles Stabilized by Carbon Nanotubes

A Study of the Complexation of Mercury(II) with Dicysteinyl Tetrapeptides by Electrospray Ionization Mass Spectrometry

Preparation of Macroporous Epitaxial Quartz Films on Silicon by Chemical Solution Deposition

Facile Preparation of 4-Substituted Quinazoline Derivatives

Facile Synthesis of Worm-like Micelles by Visible Light Mediated Dispersion Polymerization Using Photoredox Catalyst

Sulfate Separation by Selective Crystallization with a Bis-iminoguanidinium Ligand

Facile Preparation of Ultrafine Aluminum Hydroxide Particles with or without Mesoporous MCM-41 in Ambient Environments

Facile Protocol for the Synthesis of Self-assembling Polyamine-based Peptide Amphiphiles (PPAs) and Related Biomaterials

Read Article