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February 04, 2013
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הליך פשוט להכנה של סמריום diiodide (SMI<sub> 2</sub>) בTHF מתואר. התפקיד של שני תוספים עיקריים כלומר hexamethylphosphoramide (HMPA) וניקל (acac)<sub> 2</sub> בSm תגובות מתווכות מודגמות בתגובת SM-Barbier.
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Sadasivam, D. V., Choquette, K. A., Flowers II, R. A. Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction. J. Vis. Exp. (72), e4323, doi:10.3791/4323 (2013).
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