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对映草非活化氮丙啶的制备及比咪咪唑B、D和 表皮异毒羯碱的合成
JoVE Journal
Kimya
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JoVE Journal Kimya
Preparation of Enantiopure Non-Activated Aziridines and Synthesis of Biemamide B, D, and epiallo-Isomuscarine
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对映草非活化氮丙啶的制备及比咪咪唑B、D和 表皮异毒羯碱的合成

DOI:
10.3791/63705-v

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11:04 min

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June 13, 2022

•

,
1Kimya Bölümü,Hankuk University of Foreign Studies

Bölümler

  • 00:04Introduction
  • 01:31Synthesis of the Diastereomeric Mixture of Chiral Aziridine (-)-Mentholyl Ester Derivative
  • 06:38Regio and Stereoselective Aziridine Ring-Opening by Azide Nucleophile for the Total Synthesis of Biemamide B and Biemamide D
  • 08:33Results: Synthesis of Aziridine-2-Carboxylates, Biemamide, and Epiallo-Isomuscarine
  • 10:16Conclusion

Özet

Otomatik Çeviri

Otomatik Çeviri

在这项研究中，我们制备了两种对映体-2-羧酸盐，用于生物碱的不对称合成，包括比咪胺B和D，以及（-）-表皮异毒羯碱。

Etiketler

Enantiopure AziridinesBiemamide BBiemamide DEpiallo-isomuscarineAsymmetric SynthesisCrystallizationLarge-scale PreparationNon-activated AziridinesAziridine-2 Carboxylate

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