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Construction de peptides cycliques à l’aide d’un centre de sulfonium sur attache
 
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Construction de peptides cycliques à l’aide d’un centre de sulfonium sur attache

Article DOI: 10.3791/64289-v • 07:11 min • September 28th, 2022
September 28th, 2022 •
*1, *1,2, *1, 3, 1,2, 1, 3, 1,2, 1,2
1Pingshan Translational Medicine Center, Shenzhen Bay Laboratory, 2Key Laboratory of Chemical Genomics, School of Chemical Biology and Biotechnology, Peking University Shenzhen Graduate School, 3Department of Radiation Oncology, the First Affiliated Hospital, Anhui Medical University
* These authors contributed equally

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Ce protocole présente la synthèse de peptides cycliques via la bisalkylation entre la cystéine et la méthionine et la réaction thiol-yne facile déclenchée par le centre propargylsulfonium.

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Chimie numéro 187 Peptides cycliques bisalkylation/désalkylation bromure de propargyle stabilisation cystéine méthionine
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