Chapter 5
Complexometric Titration, Precipitation Titration, and Gravimetry
![Complexometric Titration: Overview](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14571.jpg)
Complexometric titration involves the formation of a complex by reacting a metal ion with one or more ligands. A visual indicator often detects the…
![Complexometric Titration: Ligands](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/15002.jpg)
Different monodentate and polydentate ligands are used as complexing agents in complexometric titration reactions. The formation of complexes by…
![EDTA: Chemistry and Properties](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14572.jpg)
Polydentate ligands are most widely used in complexometric titrations because they form more stable complexes with the metal ions than mono- or…
![EDTA: Conditional Formation Constant](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14573.jpg)
Each EDTA molecule has six binding sites: four carboxyl groups and two amino groups. The fully protonated form of EDTA is represented as H6Y2+.…
![EDTA: Direct, Back-, and Displacement Titration](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14575.jpg)
The EDTA titration types for metal ion analysis include direct titration, back-titration, and replacement titration.
Direct titration involves…
![EDTA: Indirect and Alkalimetric Titration](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14730.jpg)
Unlike direct titration, back-titration, and displacement titration, indirect titration is an EDTA titration method for quantifying anions. In the…
![Effects of EDTA on End-Point Detection Methods](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14577.jpg)
Different methods, such as visual observance of metal-ion indicators, spectroscopic techniques, and potentiometric methods, can determine the…
![Masking and Demasking Agents](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14578.jpg)
EDTA titrations may necessitate masking and demasking agents to temporarily protect a particular metal ion in a mixture from the EDTA reaction. These…
![Precipitation Titration Curve: Analysis](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14580.jpg)
The precipitation titration curve demonstrates the change in concentration of one reactant with the volume of titrant added. During the titration of…
![Precipitation Titration: Endpoint Detection Methods](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14581.jpg)
In argentometric precipitation titrations, endpoints can be detected visually by the Mohr, Volhard, and Fajans methods. In the Mohr method, adding a…
![Gravimetry: Inorganic And Organic Precipitating Agents](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14731.jpg)
In gravimetry, the precipitant is chosen carefully to obtain a pure solid that can be easily filtered. Common inorganic precipitants can be used to…
![Precipitation Gravimetry](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14583.jpg)
Precipitation gravimetry is based on converting an analyte into a sparingly soluble precipitate, which is separated by filtration and weighed. An…
![Precipitation Processes](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14585.jpg)
The experimental conditions in a gravimetric analysis should be optimized to maximize the particle size and purity of the obtained precipitate.…
![Colloidal precipitates](https://jovecdn2.ccindex.cn/files/media/science-education/science-education-thumbs/14586.jpg)
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large…
![Organic Solvent-Based Protein Precipitation for Robust Proteome Purification Ahead of Mass Spectrometry](https://jovecdn2.ccindex.cn/files/thumbs/63503_t.png)
While multiple advances in mass spectrometry (MS) instruments have improved qualitative and quantitative proteome analysis, more reliable front-end…
![Determination of Carbonyl Functional Groups in Bio-oils by Potentiometric Titration: The Faix Method](https://jovecdn2.ccindex.cn/files/thumbs/55165_t.png)
Determination of Carbonyl Functional Groups in Bio-oils by Potentiometric Titration: The Faix Method
Carbonyl compounds present in bio-oils are known to be responsible for bio-oil property changes upon storage and during upgrading. Specifically,…
![Collection and Analysis of <em>Arabidopsis</em> Phloem Exudates Using the EDTA-facilitated Method](https://jovecdn2.ccindex.cn/files/thumbs/51111_t.png)
Collection and Analysis of Arabidopsis Phloem Exudates Using the EDTA-facilitated Method
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The plant phloem is essential for the long-distance transport of (photo-) assimilates as well as of signals conveying biotic or abiotic stress. It…