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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
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JoVE Journal Chemistry
Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)

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10,570 Views

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10:42 min

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December 29, 2016

DOI:

10.3791/54789-v

DOI:
10.3791/54789-v

•

10:42 min
December 29, 2016

•

2 Views
, , ,
1Department of Chemistry,University of California, Berkeley, 2Fachbereich Chemie,Philipps-Universität Marburg and Wissenschaftliches Zentrum für Materialwissenschaften

Summary

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The synthesis of chalcogenidoplumbates(II,IV) via the in situ reduction of nominal "PbCh2" (Ch = Chalcogen) and via a solid-state reaction and subsequent solvothermal reactions is presented. Additionally, reactivities of plumbate(II) solutions are portrayed, which yield the heaviest-known CO homolog known to date: the µ-PbSe ligand.

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Thiele, G., Donsbach, C., Nußbruch, I., Dehnen, S. Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV). J. Vis. Exp. (118), e54789, doi:10.3791/54789 (2016).

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