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Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
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JoVE Journal Chemistry
Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst

DOI:
10.3791/53571-v

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06:49 min

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April 22, 2016

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, , , ,
1Department of Chemistry and Biochemistry,University of Colorado Boulder

Chapters

  • 00:05Title
  • 00:58Photopolymerization of Methyl Methacrylate Using Perylene as the Photocatalyst
  • 02:02Kinetic Analysis of the Reaction and Isolation and Purification of the Product Polymer
  • 04:33Chain-extension of an MMA Macroinitiator with Styrene to Produce Poly(MMA)-b-poly(S)
  • 05:42Results: Polymerization of Methyl Methacrylate and Block Copolymerization from a Methyl Methacrylate Macroinitiator
  • 06:21Conclusion

Summary

Automatic Translation

Automatic Translation

A method for the atom transfer radical polymerization of functionalized vinyl monomers using perylene as a visible-light photocatalyst is described.

Tags

Atom Transfer Radical PolymerizationPeryleneVisible Light PhotocatalystPolymethyl MethacrylateOrganic CatalysisPhotoredox CatalysisTransition Metal ComplexesOrganic DyesReaction SetupReproducibilityReagent PreparationNitrogen AtmosphereIlluminationInitiationQuenchingNMR Spectroscopy

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