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Mizoroki-哎呀交叉偶联反应由二氯{双[1,1'，1'' - （phosphinetriyl）tripiperidine]}钯催化在温和的反应条件
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Chemistry
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JoVE Journal Chemistry
Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1′,1”-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-哎呀交叉偶联反应由二氯{双[1,1'，1'' - （phosphinetriyl）tripiperidine]}钯催化在温和的反应条件

English

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24,984 Views

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11:44 min

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March 20, 2014

DOI:

10.3791/51444-v

DOI:
10.3791/51444-v

•

11:44 min
March 20, 2014

•

12 Views
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1Institute of Inorganic Chemistry,University of Zürich, 2Institute of Chemistry & Biological Chemistry,Zürich University of Applied Sciences

Summary

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二氯{双[1,1'，1'' - （phosphinetriyl）tripiperidine]}钯[（P（NC 5 H 10）3）2的Pd（CL）2]（1）是一种简单方便，价格便宜，而且空气稳定，但是高活性催化剂的Heck用温和的反应条件下，有效地操作，得到偶联产物在非常高的产率优良的官能团耐受性。

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Heck ReactionMizoroki-Heck Cross-couplingPalladium CatalystDichloro{bis[11′1”-(phosphinetriyl)tripiperidine]}palladiumAir-stable CatalystMild Reaction ConditionsCatalyst SynthesisHeck Reaction Protocol

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Oberholzer, M., Frech, C. M. Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions. J. Vis. Exp. (85), e51444, doi:10.3791/51444 (2014).

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