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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1′,1”-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
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Química
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JoVE Journal Química
Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1′,1”-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1′,1”-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

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11:44 min

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March 20, 2014

DOI:

10.3791/51444-v

DOI:
10.3791/51444-v

•

11:44 min
March 20, 2014

•

12 Views
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1Institute of Inorganic Chemistry,University of Zürich, 2Institute of Chemistry & Biological Chemistry,Zürich University of Applied Sciences

Summary

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Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium [(P(NC5H10)3)2Pd(Cl)2] (1) is an easy accessible, cheap, and air stable, but highly active Heck catalyst with an excellent functional group tolerance that efficiently operates under mild reaction conditions to give the coupling products in very high yields.

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Heck ReactionMizoroki-Heck Cross-couplingPalladium CatalystDichloro{bis[11′1”-(phosphinetriyl)tripiperidine]}palladiumAir-stable CatalystMild Reaction ConditionsCatalyst SynthesisHeck Reaction Protocol

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Cite this Article

Oberholzer, M., Frech, C. M. Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions. J. Vis. Exp. (85), e51444, doi:10.3791/51444 (2014).

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