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位置選択的開環反応のための連続ビサジリジンの調製
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JoVE Journal Kimya
Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
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位置選択的開環反応のための連続ビサジリジンの調製

2,751 Views

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04:38 min

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July 28, 2022

DOI:

10.3791/64019-v

DOI:
10.3791/64019-v

•

04:38 min
July 28, 2022

•

1 Views
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1Department of Energy Science,Sungkyunkwan University, 2Kimya Bölümü,Hankuk University of Foreign Studies

Özet

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非活性化および活性化アジリジンを含む連続したビサジリジンを不斉有機触媒アジリジン化によって合成し、次いで酸性または塩基性条件下で化学選択的開環反応を行った。非活性化アジリジン環は酸性条件下では反応性の低い求核剤で開環しますが、活性化されたアジリジン環は塩基性条件下でより反応性の高い求核剤で開きます。

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Cite this Article

Lee, Y., Byeon, H., Ha, H., Yang, J. W. Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions. J. Vis. Exp. (185), e64019, doi:10.3791/64019 (2022).

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