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用于区域选择性开环反应的连续双氮丙啶的制备
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JoVE Journal Kimya
Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions
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用于区域选择性开环反应的连续双氮丙啶的制备

2,751 Views

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04:38 min

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July 28, 2022

DOI:

10.3791/64019-v

DOI:
10.3791/64019-v

•

04:38 min
July 28, 2022

•

1 Views
, , ,
1Department of Energy Science,Sungkyunkwan University, 2Kimya Bölümü,Hankuk University of Foreign Studies

Özet

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通过不对称有机催化氮丙啶合成含有未活化和活化氮杂环啶的连续双氮丙啶，然后在酸性或碱性条件下进行化学选择性开环反应。在酸性条件下，未活化的氮丙啶环以较少的反应性亲核试剂打开，而活化的氮丙啶环在碱性条件下以反应性较高的亲核试剂打开。

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Cite this Article

Lee, Y., Byeon, H., Ha, H., Yang, J. W. Preparation of Contiguous Bisaziridines for Regioselective Ring-Opening Reactions. J. Vis. Exp. (185), e64019, doi:10.3791/64019 (2022).

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