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Preparation and Use of Carbonyl-decorated Carbenes in the Activation of White Phosphorus
Bölümler
- 00:05Başlık
- 01:51Synthesis of Diamidocarbene
- 06:58Synthesis of a Tris(phosphaalkenyl)phosphane
- 08:19Synthesis of a Carbene-stabilized P8 Allotrope
- 09:39Trapping a Transient E-1,2-bis(phosphaalkenyl)diphosphene via [4+2] Cycloaddition
- 11:21Results: Synthesis and Characterization of Carbonyl-decorated Carbenes and Activation of White Phosphorous
- 13:38Conclusion
Here, we present a protocol for the synthesis of two carbonyl-decorated carbenes. The protocol makes these interesting compounds readily available to chemists of all skill levels. In addition to the synthesis of these two carbenes, their use in the activation of white phosphorus is also described.
