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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
JoVE Journal
Química
This content is Free Access.
JoVE Journal Química
Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
DOI:

07:36 min

November 09, 2019

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Capítulos

  • 00:05Título
  • 00:57Compound 2 Synthesis
  • 02:46Compound 3 Synthesis
  • 04:07Compound 4 Synthesis
  • 05:34Results: Representative 1H NMR Analyses of Compounds 1 – 4
  • 06:59Conclusion

Summary

Tadução automática

CO2 transformations are conducted in a one-pot two-step procedure for the synthesis of complex molecules. The selective 4 e- reduction of CO2 with a hydroborane reductant affords a reactive and versatile bis(boryl)acetal intermediate which is subsequently involved in condensation reaction or carbene-mediated C-C coupling generation.

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