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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
JoVE Journal
Chimica
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JoVE Journal Chimica
Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

7,695 Views

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07:36 min

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November 09, 2019

DOI:

10.3791/60348-v

DOI:
10.3791/60348-v

•

07:36 min
November 09, 2019

•

4 Views
, , ,
1LCC-CNRS,Université de Toulouse, CNRS, 2LISBP,Université de Toulouse, CNRS, INRA, INSA

Summary

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CO2 transformations are conducted in a one-pot two-step procedure for the synthesis of complex molecules. The selective 4 e- reduction of CO2 with a hydroborane reductant affords a reactive and versatile bis(boryl)acetal intermediate which is subsequently involved in condensation reaction or carbene-mediated C-C coupling generation.

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Desmons, S., Zhang, D., Mejia Fajardo, A., Bontemps, S. Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy. J. Vis. Exp. (153), e60348, doi:10.3791/60348 (2019).

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