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Chapter 10

遷移金属と配位錯体

Chapter 10

Transition Metals and Coordination Complexes

Transition metals are defined as those elements that have partially filled d orbitals. As shown in Figure 1, the d-block elements in groups 3–12 are …
In most main group element compounds, the valence electrons of the isolated atoms combine to form chemical bonds that satisfy the octet rule. For …
For transition metal complexes, the coordination number determines the geometry around the central metal ion. Table 1 compares coordination numbers to …
Isomerism in Complexes Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be …
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which …
Crystal Field Theory To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between …
This article shows how the COLTRIMS (Cold Target Recoil Ion Momentum Spectroscopy) or the “reaction microscope” technique can be used to distinguish …
The size, size distribution and stability of colloidal nanoparticles are greatly affected by the presence of capping ligands. Despite the key contribution …
Chemical model complexes are prepared to represent the active site of an enzyme. In this protocol, a family of tridentate pincer ligand precursors (each …