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Synthesis of Low-Valent MOFs from Multitopic Phosphine Linkers

Synthesis of Low-Valent MOFs from Multitopic Phosphine Linkers

May 12, 2023

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

01:43 min
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Synthesis and Isolation of the MOF Product

04:34 min
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Characterization of the MOF Product by Powder X-Ray Diffraction (PXRD)

01:16 min
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1Department of Chemistry and Biochemistry,University of California, San Diego

概要

Here, we describe a protocol for the synthesis of low-valent metal-organic frameworks (LVMOFs) from low-valent metals and multitopic phosphine linkers under air-free conditions. The resulting materials have potential applications as heterogeneous catalyst mimics of low-valent metal-based homogeneous catalysts.

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