È necessario avere un abbonamento a JoVE per visualizzare questo. Accedi o inizia la tua prova gratuita.
Capitoli
- 00:04Titolo
- 00:47Drying/Purification of ε-caprolactone
- 03:50Ring Opening Polymerization of ε-caprolactone
- 05:06RAFT (Reversible Addition-Fragmentation chain-Transfer) Polymerization of MMA (Methyl Methacrylate) and N,N-dimethylacrylamide
- 08:00Self-nucleation, Seed Generation and Living Crystallization-driven Self-assembly
- 09:34Results: 1H NMR Spectrum and GPC
- 11:11Conclusion
Crystallization-driven self-assembly (CDSA) displays the unique ability to fabricate cylindrical nanostructures of narrow length distributions. The organocatalyzed ring-opening polymerization of ε-caprolactone and subsequent chain extensions of methyl methacrylate and N,N-dimethyl acrylamide are demonstrated. A living CDSA protocol that produces monodisperse cylinders up to 500 nm in length is outlined.
