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Exfoliation of Egyptian Blue and Han Blue, Two Alkali Earth Copper Silicate-based Pigments
JoVE Journal
Chimica
This content is Free Access.
JoVE Journal Chimica
Exfoliation of Egyptian Blue and Han Blue, Two Alkali Earth Copper Silicate-based Pigments
DOI:

12:04 min

April 24, 2014

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Capitoli

  • 00:05Titolo
  • 01:16Melt Flux Synthesis of CaCuSi4O10
  • 03:02Solid State Synthesis of CaCuSi4O10
  • 03:57Exfoliation of CaCuSi4O10 and Ink Preparation
  • 05:29Melt Flux Synthesis of BaCuSi4O10
  • 06:38Solid State Synthesis of BaCuSi4O10
  • 07:24Exfoliation of BaCuSi4O10
  • 08:41Near Infrared Photographic Imaging
  • 09:12Results: Optical, Scanning Electron, and Powder X-ray Diffraction Characterization of Synthesized CaCuSi4O10and BaCuSi4O10
  • 11:38Conclusion

Summary

Traduzione automatica

The preparation and exfoliation of CaCuSi4O10 and BaCuSi4O10 are described. Upon stirring in hot water, CaCuSi4O10 spontaneously exfoliates into monolayers, whereas BaCuSi4O10 requires ultrasonication in organic solvents. Near infrared (NIR) imaging illustrates the NIR emission properties of these materials, and aqueous dispersions of these nanomaterials are useful for solution processing.

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