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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1′,1”-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
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Chimie
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Journal JoVE Chimie
Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1′,1”-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1′,1”-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

DOI:
10.3791/51444-v

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11:44 min

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March 20, 2014

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,
1Institute of Inorganic Chemistry,University of Zürich, 2Institute of Chemistry & Biological Chemistry,Zürich University of Applied Sciences

Chapitres

  • 00:05Titre
  • 02:37Ligand Synthesis (1,1′,1″-(Phosphinetriyl)tripiperidine)
  • 04:18Catalyst Synthesis (Dichloro{bis[1,1′,1″-(phosphinetriyl)tripiperidine]}palladium)
  • 06:02Heck Reaction Catalyzed by Dichloro{bis[1,1′,1″-(phosphinetriyl)tripiperidine]}palladium
  • 09:17Results: Mizoroki-Heck Reaction Catalyzed by Dichloro{bis[1,1′,1″-(phosphinetriyl)tripiperidine]}palladium
  • 11:15Conclusion

Summary

Traduction automatique

Traduction automatique

Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium [(P(NC5H10)3)2Pd(Cl)2] (1) is an easy accessible, cheap, and air stable, but highly active Heck catalyst with an excellent functional group tolerance that efficiently operates under mild reaction conditions to give the coupling products in very high yields.

Tags

Heck ReactionMizoroki-Heck Cross-couplingPalladium CatalystDichloro{bis[11′1”-(phosphinetriyl)tripiperidine]}palladiumAir-stable CatalystMild Reaction ConditionsCatalyst SynthesisHeck Reaction Protocol

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