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One-pot Microwave-assisted Conversion of Anomeric Nitrate-esters to Trichloroacetimidates
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JoVE Journal Chemistry
One-pot Microwave-assisted Conversion of Anomeric Nitrate-esters to Trichloroacetimidates

One-pot Microwave-assisted Conversion of Anomeric Nitrate-esters to Trichloroacetimidates

DOI:
10.3791/56610-v

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06:00 min

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January 15, 2018

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, , ,
1Department of Chemistry,Vanderbilt University, 2Institute of Chemical-Biology,Vanderbilt University

Chapters

  • 00:05Title
  • 00:34Microwave-assisted Denitration of 2-Azido-1-nitrate Esters and Trichloroacetimide Formation
  • 03:18Results: Microwave-assisted Conversion of Anomeric Nitrate Esters to Trichloroacetimidates
  • 05:03Conclusion

Summary

Automatic Translation

Automatic Translation

A 2-azido-1-nitrate-ester can be converted to the corresponding 2-azido-1-trichloroacetimidate in a one-pot procedure. The goal of the manuscript is to demonstrate utility of the microwave reactor in carbohydrate synthesis.

Tags

Keywords: One-potMicrowave-assistedConversionAnomericNitrate-estersTrichloroacetimidatesOligosaccharide SynthesisAzido Nitrate-estersPyridineMicrowave ReactorTLCDichloromethaneDBUTrichloroacetonitrileSilica Gel Column ChromatographyAlpha ManolAlpha GlucoBeta Gluco

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