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Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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JoVE Journal Chemie
Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

DOI:
10.3791/56654-v

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05:48 min

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November 21, 2017

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,
1Center for Molecular Systems and Organic Devices, Institute of Optoelectronic Materials, Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials,Nanjing University of Posts and Telecommunications, 2Department of Chemical Engineering,Virginia Polytechnic Institute and State University

Kapitel

  • 00:05Titel
  • 00:45Photoredox Ring-Opening Polymerization of Phenyl O-Corboxyanhydride (L-1)
  • 03:49Results: Characterization of Poly(phenyl O-Corboxyanhydride)(poly(L-1))
  • 04:59Conclusion

Summary

Automatische Übersetzung

Automatische Übersetzung

A protocol for the controlled photoredox ring-opening polymerization of O-carboxyanhydrides mediated by Ni/Zn complexes is presented.

Tags

Controlled Photoredox Ring-opening PolymerizationO-carboxyanhydridesNi/zn ComplexesPoly(alpha-hydroxy Acids)High Molecular Weight PolyestersSide Chain Functional GroupsAnhydrous THFBipy-nickel(COD)Zinc Bis(hmds)Benzyl AlcoholIridium CatalystL1 MonomerBlue LED LightTemperature Control

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