Chemical Precipitation Method for the Synthesis of Nb<sub>2</sub>O<sub>5</sub> Modified Bulk Nickel Catalysts with High Specific Surface Area

Chuang Li; Shaohua Jin; Weixiang Guan; Chi-Wing Tsang; Wing-Kin Chu; Wai Kin Lau; Changhai Liang

doi:10.3791/56987

JoVE Journal > Chemistry

Chemie

Chemical Precipitation Method for the Synthesis of Nb₂O₅ Modified Bulk Nickel Catalysts with High Specific Surface Area

Published: February 19, 2018

doi:

10.3791/56987

Chuang Li¹, Shaohua Jin¹, Weixiang Guan¹, Chi-Wing Tsang², Wing-Kin Chu², Wai Kin Lau², Changhai Liang¹

¹Laboratory of Advanced Materials and Catalytic Engineering, School of Chemical Engineering,Dalian University of Technology, ²Faculty of Science and Technology,Technological and Higher Education Institute of Hong Kong

Summary

A protocol for the synthesis of sponge-like and fold-like Ni_1-xNb_xO nanoparticles by chemical precipitation is presented.

Abstract

We demonstrate a method for the synthesis of Ni_xNb_1-xO catalysts with sponge-like and fold-like nanostructures. By varying the Nb:Ni ratio, a series of Ni_xNb_1-xO nanoparticles with different atomic compositions (x = 0.03, 0.08, 0.15, and 0.20) have been prepared by chemical precipitation. These Ni_xNb_1-xO catalysts are characterized by X-ray diffraction, X-ray photoelectron spectroscopy, and scanning electron microscopy. The study revealed the sponge-like and fold-like appearance of Ni_0.97Nb_0.03O and Ni_0.92Nb_0.08O on the NiO surface, and the larger surface area of these Ni_xNb_1-xO catalysts, compared with the bulk NiO. Maximum surface area of 173 m²/g can be obtained for Ni_0.92Nb_0.08O catalysts. In addition, the catalytic hydroconversion of lignin-derived compounds using the synthesized Ni_0.92Nb_0.08O catalysts have been investigated.

Introduction

The preparation of nanocomposites has received increasing attention due to their crucial application in various field. To prepare Ni-Nb-O mixed oxide nanoparticles,¹^,²^,³^,⁴^,⁵^,⁶ different methods have been developed such as dry mixing method,⁷^,⁸ evaporation method,⁹^,¹⁰^,¹¹^,¹²^,¹³ sol gel method,¹⁴ thermal decomposition method,¹⁵ and auto-combustion.¹⁶ In a typical evaporation method⁹, aqueous solutions containing the appropriate amount of metal precursors, nickel nitrate hexahydrate and ammonium niobium oxalate were heated at 70 °C. After the removal of solvent and further drying and calcination, the mixed oxide was obtained. These oxide catalysts exhibit excellent catalytic activity and selectivity towards the oxidative dehydrogenation (ODH) of ethane, which is related to the electronic and structural rearrangement induced by the incorporation of niobium cations in the NiO lattice.¹¹ The insertion of Nb drastically decreases the electrophilic oxygen species, which is responsible for the oxidation reactions of ethane¹². As a result, extensions of this method have been done on the preparation of different types of mixed Ni-Me-O oxides, where Me = Li, Mg, Al, Ga, Ti and Ta.¹³ It is found that the variation of metal dopants could alter the unselective and electrophilic oxygen radicals of NiO, thus systematically tune the ODH activity and selectivity towards ethane. However, generally the surface area of these oxides is relatively small (< 100 m²/g), due to the extended phase segregation and formation of large Nb₂O₅ crystallites, and thus hampered their uses in other catalytic applications.

Dry mixing method, also known as the solid-state grinding method, is another commonly used method to prepare the mixed-oxide catalysts. Since the catalytic materials are obtained in a solvent-free way, this method provides a promising green and sustainable alternative to the preparation of mixed-oxide. The highest surface area obtained by this method is 172 m²/g for Ni₈₀Nb₂₀ at calcination temperature of 250 °C.⁸ However, this solid-state method is not reliable as reactants are not well mixed on the atomic scale. Therefore, for better control of chemical homogeneity and specific particle size distribution and morphology, other suitable methods to prepare Ni-Nb-O mixed oxide nanoparticles are still being sought.⁷

Among various strategies in the development of nanoparticles, chemical precipitation serves as one of the promising methods to develop the nanocatalysts, since it allows the complete precipitation of the metal ions. Also, nanoparticles of higher surface areas are commonly prepared by using this method. To improve the catalytic properties of Ni-Nb-O nanoparticles, we herein report the protocol for the synthesis of a series of Ni-Nb-O mixed oxide catalysts with high surface area by chemical precipitation method. We demonstrated that the Nb:Ni molar ratio is a crucial factor in determining the catalytic activity of the oxides towards the hydrodeoxygenation of lignin-derived organic compounds. With high Nb:Ni ratio above 0.087, inactive NiNb₂O₆ species were formed. Ni_0.92Nb_0.08O, which had the largest surface area (173 m²/g), exhibits fold-like nanosheets structures and showed the best activity and selectivity towards the hydrodeoxygenation of anisole to cyclohexane.

Protocol

Caution: For the proper handling methods, properties and toxicities of the chemicals described in this paper, refer to the relevant material safety data sheets (MSDS). Some of the chemicals used are toxic and carcinogenic and special cares must be taken. Nanomaterials may potentially pose safety hazards and health effects. Inhalation and skin contact should be avoided. Safety precaution must be exercised, such as performing the catalyst synthesis in the fume hood and catalyst performance evaluation with autoclave reactors. Personal protective equipment must be worn.

1. Preparation of Ni_0.97Nb_0.03O Catalysts where Nb:(Ni+Nb) molar ratios equal to 0.03

Combine 0.161 g of niobium (V) oxalate hydrate with 2.821 g of nickel nitrate in 100 mL of deionized water in a 250-mL three-necked round bottom flask equipped with a stir bar.
Stir the solution at 50 rpm and 70 °C to dissolve the compounds until the disappearance of precipitate using a heating magnetic stirrer.
Raise the temperature rapidly to 80 °C at a rate of 2 °C/min.
Add a mixed basic solution [aqueous ammonium hydroxide (50 mL, 1.0 M) and sodium hydroxide (50 mL, 0.2 M)] into the reaction mixture dropwise until the pH of the Ni/Nb solution reaches 9.0.
While stirring the reaction mixture, raise the temperature to 120 °C at 2 °C/min.
Stir the reaction mixture overnight at 50 rpm at 120 °C until the complete disappearance of the green color of the solution.
Perform inductively coupled plasma-optical emission spectrometry (ICP-OES) analysis for the solution to evaluate the concentration of remaining Ni²⁺and Nb⁵⁺ions in the solution and ensure the complete precipitation of remaining nickel nitrate.
Collect the solid by filtration using Büchner flask. Wash the solid by adding 2 L deionized water repeatedly within 20 min to remove the residual Na⁺ cation.
Collect the solid in a watch glass. Dry the solid at 110 °C for 12 h in dry oven.
Calcine by heating the solids in synthetic air (20 mL/min O₂ and 80 mL/min N₂) at 450 °C for 5 h in tube furnace. Check all glassware for defect prior to use the high temperature of reaction.
After the calcination, obtain 1 g of Ni_0.97Nb_0.03O catalyst. Use appropriate protective equipment such as safety glasses, gloves, lab coat, and fume hood to perform the nanocrystal reaction due to potential safety hazards and health effects of the nanomaterials.

2. Preparation of Ni_0.92Nb_0.08O Catalysts where Nb:(Ni+Nb) molar ratios equal to 0.08

This procedure is similar to that of 1 except for the first two steps:
1. Dissolve 0.43 g of niobium (V) oxalate hydrate in 100 mL of deionized water.
2. Separately, dissolve 2.675 g of nickel nitrate in 100 mL of deionized water.

3. Preparation of Ni_0.85Nb_0.15O Catalysts where Nb:(Ni+Nb) molar ratios equal to 0.15

The procedure is similar to that of 1 except for the first two steps:
1. Dissolve 0.807 g of niobium (V) oxalate hydrate in 100 mL of deionized water.
2. Separately, dissolve 2.472 g of nickel nitrate in 100 mL of deionized water.

4. Preparation of Ni_0.80Nb_0.20O Catalysts where Nb:(Ni+Nb) molar ratios equal to 0.20

The procedure is similar to that of 1 except for the first two steps:
1. Dissolve 1.076 g of niobium (V) oxalate hydrate in 100 mL of deionized water.
2. Separately, dissolve 2.326 g of nickel nitrate in 100 mL of deionized water.

5. Preparation of Nb₂O₅ using chemical precipitation method

Calcine niobic acid (Nb₂O₅·nH₂O) in synthetic air for 5 h at 450 °C to obtain pure Nb₂O₅ particles.
NOTE: Confirm the completion of reaction using X-ray powder diffraction (XRD) analysis, where Nb₂O₅·nH₂O is Amorphous and Nb₂O₅ is crystalline. According to the analysis, the calcination for 5 h at 450 °C was enough to complete the reaction.

6. Synthesis of β-O-4 lignin model compound, 2-(2-methoxyphenoxy)-1-phenylethan-1-one

Dissolve bromoacetophenone (9.0 g, 45 mmol) and 2-methoxyphenol (6.6 g, 53 mmol) in 200 mL of dimethylformamide (DMF) in a 500-mL conical flask with a magnetic stirrer. Use appropriate protective equipment and fume hood to perform the reaction using corrosive and carcinogenic chemicals and reagents.
Mix the above DMF solution with potassium hydroxide (3.0 g, 53 mmol) and stir the mixture overnight at 50 rpm at room temperature using magnetic stirrers.
Extract the product with the mixture solution of 200 mL of H₂O and 600 mL of diethyl ether (1:3, v/v) using separation funnel. Obtain the upper diethyl ether layer of the solution.
Add MgSO₄ (10 g) to absorb moisture of the diethyl ether solution. Filter the MgSO₄to obtain the diethyl ether solution by using filter paper and funnel.
After removal of the diethyl ether solution under reduced pressure at 0.08 MPa using rotary evaporator, dissolve the residue in 5 mL of ethanol.
Slowly evaporate the ethanol solvent to recrystallize the product in a 10-mL beaker. Obtain the product (11.5 g) as yellowish powder and the yield of product is 90% based on bromoacetophenone. From the ¹H NMR analysis, ¹H NMR (DMSO): δ 3.78 (s, 3H, OCH₃), 5.54 (s, 2H, CH₂), 6.82-8.01 (m, 9H, aromatic) ppm.¹⁷

7. Hydrodeoxygenation of Lignin-derived Aromatic Ether

NOTE: The chosen lignin-derived aromatic ether is anisole in this experiment and the catalyst is Ni_0.92Nb_0.08O. Use appropriate protective equipment and fume hood to perform the reaction using carcinogenic reagents.

Equip a 50-mL stainless steel autoclave reactor with a heater and a magnetic stirrer.
Reduce the Ni_0.92Nb_0.08O catalyst (1 g) obtained from step 2 in the autoclave reactor in H₂ atmosphere at 400 °C for 2 h, and then passivate the catalyst under Argon (50 mL/min) overnight.
Dissolve anisole (1.1712 g, 8 wt%) into n-decane (20 mL) with the use of n-dodecane (0.2928 g, 2 wt%) as an internal standard for quantitative gas chromatography (GC) analysis.
Introduce the reduced catalysts (0.1 g) in into the autoclave reactor rapidly to avoid long exposure time with air (< 5 mins).
Seal the autoclave reactor, purge with H₂ repeatedly (3 times, at 3 MPa pressure) to eliminate air, and then the reaction mixture at atmosphere pressure.
Set the stirring speed at 700 rpm.
After heating to the desired temperature at 160-210 °C at 2 °C/min, pressurize the autoclave reactor to 3 MPa and set the zero-time point (t = 0).
NOTE: The temperature range of 160-210 °C is appropriate in this report.
Subsequently, cool the mixture to room temperature at 10 °C/min immediately and analyze the deoxygenated products using gas chromatography with mass selective detector.¹⁷
Determine the conversion of lignin model compound according to the following equation:
Determine the product selectivity according to the following equation:

Representative Results

X-ray diffraction (XRD) patterns (Figure 1 and Figure 2), BET surface areas, temperature-programmed reduction of hydrogen with hydrogen (H₂-TPR), scanning electron microscopy (SEM) equipped with an energy-dispersive X-ray (EDX) analyzer, X-ray photoelectron spectroscopy (XPS) were collected for the nanoparticles NiO, Ni-Nb-O and Nb₂O₅ oxides¹⁷ (Figure 3 and Figure 4). XRD, SEM and XPS are used to determine the phase and morphology of the nanostructures. The physicochemical properties of Ni-Nb-O mixed oxides were collected in Table 1.¹⁷

The structure of the catalysts has been previously reported and discussed.¹⁷ The X-ray diffraction pattern collected for the mixed-oxide formed by chemical precipitation of nickel nitrate and hydrated niobium (V) oxalate (Figure 1), is in good agreement with that observed for hydrated nickel oxalate (JCPDS 25-0581). After calcination with mixed-oxide precipitates for 2 h at 700 °C, the peaks observed at 2θ of 26.8°, 35.2° and 52.9° (JCPDS 76-2355) are corresponding to crystalline NiNb₂O₆ phase.

The X-ray diffraction pattern collected for the synthesized Ni_xNb_1-xO nanoparticle after calcination for 5 h at 450 °C (Figure 2), display main diffraction peaks located at 2θ of 37.1°, 43.2°, 62.5°, 74.8° and 78.7°, correspond to the (111), (200), (220), (311) and (222) reﬂections, respectively. This is in a good agreement of the crystalline NiO bunsenite structure (JCPDS 89-7130). Besides, it is clearly noted that a low intensity broad background peak appears at about 26° with increases in Nb loading, which is attributed to the emergence of the amorphous niobium oxides as a result of the chemical precipitation possessing of Nb⁵⁺ and hydroxyl ion¹⁸. Upon calcination at 700 °C, the peaks corresponding to Ni-Nb-O mixed phase are observed in the X-ray diffraction pattern of Ni_0.8Nb_0.2O, which indicate that the existence of amorphous after calcination at 450 °C,¹⁹ but not the crystalline Ni-Nb composite phase. It was documented that high % of Nb could lead to the formation of mixed phase Ni-Nb-O, e.g. NiNb₂O₆, Ni₃Nb₂O₈ and Ni₄Nb₂O₉, which would decrease the catalytic capability.

Scanning electron microscopy analysis show the dramatically different surface morphology of the Ni_xNb_1-xO nanoparticles from NiO (Figure 3). In contrast to the well-deﬁned nanosheet crystalline structures of the Pure NiO, fold-like and sponge-like appearance are clearly observed on the sheet-like NiO surface with small void spaces for Ni_0.97Nb_0.03O and Ni_0.92Nb_0.08O, respectively.⁹ The sponge-like species are identified as the Ni-Nb solid solution due to the incorporation of the Nb in the NiO lattice structure, as a result of the comparable ionic radius of Ni²⁺ (0.69 Å) and Nb⁵⁺ (0.64 Å) cations.⁹^,²⁰ As a result, sponge-/block-like appearance and round crystallites with fewer number of small void spaces are observed for the Ni_0.85Nb_0.15O and Ni_0.8Nb_0.2O nanoparticles due to the increased Nb content in the sample. In addition, the energy-dispersive X-ray maps show that the niobium oxide are well-dispersed over the bulk NiO sample (Figure 4). Its niobium-enriched surface is further confirmed by the larger surface Nb:Ni ratio of Ni_0.92Nb_0.08O sample (0.11/0.92), compared with bulk theoretical value (0.08/0.92). This can be explained by the fact that the surface of the as-prepared Ni-Nb-O is enriched with Ni nanoparticles.

The catalytic performance of this as-prepared Ni-Nb-O metal oxide was tested with the hydrodeoxygenation of anisole as the model reaction. The reaction was performed in an autoclave reactor at 3 MPa and at 160 °C. 0.1 g of Ni_0.92Nb_0.08O catalyst was placed in a mixture of 8 wt % anisole and 20 mL n-decane. After 2 h, 95.3 % conversion was obtained with 31.8 % selectivity from anisole to cyclohexane. After 12 h, the anisole was completely converted to pure cyclohexane. Instead of extending the reaction time, the effect of temperature on the catalytic performance was also investigated. Within 2 h, anisole was completely converted to cyclohexane if the temperature was set at 200 °C instead of 160 °C. Current effort has been focused on the conversion of other lignin-derived model compound with higher molecular weight to investigate the hydrodeoxygenation ability of such catalyst.

Figure 1. XRD patterns of precipitate formed by mixing nickel nitrate and niobium (V) oxalate hydrate in water at 70 °C and after calcination at 700 °C. JCPDS is Joint Committee on Powder Diffraction Standards Database. JCPDS 76-2355 is the Standard XRD reference patterns for NiNb₂O₆ materials. JPCDS 25-0581 is the Standard XRD reference patterns for nickel oxalate hydrate materials. This figure has been modified from Shaohua Jin et al.¹⁷ Please click here to view a larger version of this figure.

Figure 2. XRD patterns of Ni-Nb-O mixed oxide catalysts after calcination at 450 °C in air for 5 h. This figure has been modified from Shaohua Jin et al.¹⁷ Please click here to view a larger version of this figure.

Figure 3. Scanning electron microscopy micrographs of NiO and Ni-Nb-O mixed oxides. This figure has been modified from Shaohua Jin et al.¹⁷ Please click here to view a larger version of this figure.

Figure 4. Scanning Electron Micrograph, X-ray maps and Energy Dispersive X-ray analysis of Scanning Electron Micrograph. a) Scanning Electron Micrograph of Ni_0.92Nb_0.08O. b) X-ray maps of Ni. c) X-ray maps of O. d) X-ray maps of Nb. e) Energy Dispersive X-ray (EDX) results of Ni_0.92Nb_0.08O sample. This figure has been modified from Shaohua Jin et al.¹⁷ Please click here to view a larger version of this figure.

Catalysts	Nb/Ni ratio	S_BET (m²/g)	d (nm)	V_total (cm³/g)	Crystallite size (nm)^a
NiO	0	136	18	0.61	9.3
Ni_0.97Nb_0.03O	0.031	158	16.5	0.65	8
Ni_0.92Nb_0.08O	0.087	173	9.6	0.41	5.4
Ni_0.85Nb_0.15O	0.176	139	12.5	0.43	11.8
Ni_0.80Nb_0.20O	0.25	110	12	0.33	14.5
Nb₂O₅·nH₂O	–	122	6.7	0.2	–
^a Determined by considering the NiO (200) peak higher intensity.

Table 1. Physicochemical properties of NiO, Nb₂O₅ and Ni-Nb-O mixed oxides. This table has been modified from Shaohua Jin et al.¹⁷

Discussion

One of the common methods to prepare the nickel-doped bulk niobium oxide nanoparticles is rotary evaporation method.⁹ By employing various pressure and temperature conditions during the process of rotary evaporation, the precipitation of Ni-Nb-O particles commerce with the slow removal of the solvent. In contrast to the rotary evaporation method, the chemical precipitation method reported in this study has received increasing attention to prepare the nanoparticles as this do not require the removal of solvents. In the typical chemical precipitation methods to prepare the nanocatalysts, alkaline solution is necessary to be added dropwise into the solution of metal salts over a long period of time.²¹ In our study, a mixture of ammonia hydroxide and sodium hydroxide solution was used as the precipitating agents. One of the critical steps in chemical precipitation method is the speed of the addition of the precipitating agent.²²^,²³ Care must be taken in controlling the speed of the addition of the precipitating agents, i.e., the basic mixtures, and it is best controlled at a rate of one drop per second. If possible, peristaltic pump can be used to precisely control the addition of the precipitating agents.

Apart from the addition rate, the control of temperature is another important key for successful precipitation as the morphology of the as-prepared metal oxides are highly dependent on the temperature used in the preparation. Though it is not clear in the correlation between the morphology of nanoparticles and their related catalytic performance, the optimization of the preparation temperature to develop the efficient nanocatalysts is essential.

As Brønsted and Lewis acid sites are necessary for HDO process to convert phenolic and oxygen-containing aromatics to hydrocarbons,¹⁷ the optimization of the acid site's amount is also critical factor to improve the catalytic properties of nanoparticles. According to the related mechanistic study in the chemical precipitation methods of nanoparticles, the amount of the Brønsted sites are highly dependent on the amount of remaining water on the catalysis.²⁴ Thus, controlling the drying periods and the calcination temperature of catalysts are also critical steps in the protocol in order to optimize the catalytic properties of the catalysts.

Compared with other common nanoparticle preparation methods, chemical precipitation method has received increasing attention to prepare the nanoparticles. It is probably because this do not require the removal of solvents in the preparation. In addition, this method is capable to promote the uniform dispersion of metal components and commonly used in the preparation of nanoparticles with relatively larger surface areas.¹⁷ However, this method is preferable to prepare metal oxide catalyst with relatively higher concentration of metal ions such as those of transition metal elements.²⁵^,²⁶^,²⁷ Thus, it is not recommended to prepare alkaline earth metal oxide using this method.

The suspension is then treated by a mixture of sodium hydroxide and ammonium hydroxide aqueous solution at pH 9 to allow the complete precipitation of residual Ni²⁺ and Nb⁵⁺ cations in the sample, followed by washing with deionized water repeatedly to remove excess Na⁺ cation. After subsequent calcination in synthetic air at 450 °C, the Ni_xNb_1-xO nanoparticles are prepared and analyzed.

Surface areas, pore volume and size collected for the synthesized Ni_xNb_1-xO (Table 1) indicate that the chemical precipitation synthesis by incorporating appropriate proportion of Nb into the NiO (Nb:Ni ratio < 0.087) could effectively increase the surface areas of the materials, since niobium oxalate is used as the precursor. This is also supported by the fact that more porous structure can be formed by the chemical decomposition of hydrated nickel oxalate with organic nature,⁹ as observed in the X-ray diffraction pattern (Figure 1). However, the surface area of Ni_xNb_1-xO decreases significantly when the Nb:Ni ratio is raised to 0.15 and 0.25. This is probably due to the formation of large block-like crystallites in the sample. Scherrer formula is used to calculate the crystallite size of all prepared mixed-oxide. It can be concluded that the size of the crystallite is closely related to the corresponding surface area. We demonstrated elsewhere that the Nb:Ni ratio is a crucial factor in determining the catalytic activity of the oxides towards the hydrodeoxygenation of lignin-derived organic compounds. With high Nb % (Nb:Ni > 0.087), inactive NiNb₂O₆ species were formed by the reaction between the amorphous phase of Nb and NiO, leading to the aggregation of NiO and thus catalyst with lower surface area was obtained. With lower Nb % (Nb:Ni ≤ 0.087), the addition of niobium oxalate can increase the surface area of the catalyst. This is attributed by the fact that the as-formed Ni oxalate retard the crystal growth of the NiO crystallites, as a result catalyst with higher specific area was obtained. On the other hand, for catalyst with lower amount of Nb, the amorphous Nb₂O₅ can promote the dispersion of NiO crystallites on the surface, thus aggregation of NiO crystallites was inhibited. The large surface area (173 m²/g) of Ni_0.92Nb_0.08O, consisting of fold-like nanosheets, showed the best activity and selectivity towards the hydrodeoxygenation of anisole to cyclohexane.

In summary, we demonstrate a chemical precipitation method to prepare the Ni-Nb-O oxide catalysts. Though this method requires relatively higher concentration of metal ions solution, it has been found to successfully prepare the nanocatalysts with higher surface areas, compared those obtained from other methods. Besides, the newly prepared nanoparticles showed excellent catalytic activity in the hydrodeoxygenation of anisole to cyclohexane. The study of their applications in other catalytic systems such as hydrogenation is currently in progress. In addition, it is anticipated that a similar strategy could be further applied in the preparation of other different mixed Ni-Me-O oxides or other nanomaterials such as those with Cu²⁺, Co²⁺ with high specific surface area for various useful applications such as oxidation of alcohol and water and catalytic coupling reactions.²⁸^,²⁹^,³⁰

Offenlegungen

The authors have nothing to disclose.

Acknowledgements

We gratefully acknowledge the financial support provided by National Key Research & Development Program of the Ministry of Science and Technology of China (2016YFB0600305), National Natural Science Foundation of China (Nos. 21573031 and 21373038), Program for Excellent Talents in Dalian City (2016RD09) and Technological and Higher Education Institute of Hong Kong (THEi SG1617105 and THEi SG1617127).

Materials

Niobium(V) oxalate hydrate, 98%	Alfa	L04481902
Nickel nitrate hexahydrate, 99%	Aladdin	N108891
Sodium hydroxide, 98%	Aladdin	S111501
Ammonium hydroxide, 23-25%	Aladdin	A112077
Anisole, 99%	Sinopharm	81001728
Diphenyl ether, 98%	Aladdin	D110644
Phenol, 98%	Sinopharm	100153008
2-Methoxyphenol, 98%	Sinopharm	30114526
Vanillin, 99.5%	Sinopharm	69024316
Potassium hydroxide, AR	Aladdin	P112284
N,N-Dimethylformamide, 99.5%	Sinopharm	40016462
2-Bromoacetophenone,98%	Aladdin	B103328
Diethyl ether,99.5%	Sinopharm	10009318
Decane,98%	Aladdin	D105231
Dodecane,99%	Aladdin	D119697
Niobic acid	CBMM	1313968
Heating and Drying Oven			DHG Series (shanghai jinghong laboratory instrument co. ltd)
Autoclave Reactor			CJF-0.05—0.1L (Dalian Tongda Equipment Technology Development Co., Ltd)
Tube furnace			SK2-1-10/12 (Luoyang Huaxulier Electric Stove Co., Ltd)
Heating magnetic stirrer			DF-101 (Yu Hua Instrument Co. Ltd.)
Rotary evaporator			RE-3000A (Shanghai Yarong Biochemical Instrument Factory)
Synthetic air
Hydrogen gas
Argon gas

Referenzen

Zhou, Y., Yang, M., Sun, K., Tang, Z., Kotov, N. A. Similar topological origin of chiral centers in organic and nanoscale inorganic structures: effect of stabilizer chirality on optical isomerism and growth of CdTe nanocrystals. J. Am. Chem. Soc. 132 (17), 6006-6013 (2010).
Zhou, Y., et al. Optical Coupling Between Chiral Biomolecules and Semiconductor Nanoparticles: Size-Dependent Circular Dichroism Absorption. Angew. Chem. Int. Ed. 50, 11456-11459 (2011).
Li, Z., et al. Reversible plasmonic circular dichroism of Au nanorod and DNA assemblies. J. Am. Chem. Soc. 134 (7), 3322-3325 (2012).
Zhu, Z., et al. Manipulation of collective optical activity in one-dimensional plasmonic assembly. ACS Nano. 6 (3), 2326-2332 (2012).
Liu, W., et al. Gold nanorod@chiral mesoporous silica core-shell nanoparticles with unique optical properties. J. Am. Chem. Soc. 135 (26), 9659-9664 (2013).
Han, B., Zhu, Z., Li, Z., Zhang, W., Tang, Z. Conformation Modulated Optical Activity Enhancement in Chiral Cysteine and Au Nanorod Assemblies. J. Am. Chem. Soc. 136, 16104-16107 (2014).
Rao, C. N. R., Gopalakrishnan, J. . New Directions in Solid State Chemistry. , (1989).
Zhu, H., Rosenfeld, D. C., Anjum, D. H., Caps, V., Basset, J. -. M. Green Synthesis of Ni-Nb Oxide Catalysts for Low-Temperature Oxidative Dehydrogenation of Ethane. ChemSusChem. 8, 1254-1263 (2015).
Heracleous, E., Lemonidou, A. A. Ni-Nb-O Mixed Oxides as Highly Active and Selective Catalysts for Ethene Production via Ethane Oxidative Dehydrogenation. Part I: Characterization and Catalytic Performance. J. Cat. 237, 162-174 (2006).
Savova, B., Loridant, S., Filkova, D., Millet, J. M. M. Ni-Nb-O Catalysts for Ethane Oxidative Dehygenation. Appl. Catal. A. 390 (1-2), 148-157 (2010).
Heracleous, E., Delimitis, A., Nalbandian, L., Lemonidou, A. A. HRTEM Characterization of the Nanostructural Features formed in Highly Active Ni-Nb-O Catalysts for Ethane ODH. Appl. Catal. A. 325 (2), 220-226 (2007).
Skoufa, Z., Heracleous, E., Lemonidou, A. A. Unraveling the Contribution of Structural Phases in Ni-Nb-O mixed oxides in Ethane Oxidative Dehydrogenation. Catal. Today. 192 (1), 169-176 (2012).
Heracleous, E., Lemonidou, A. A. Ni-Me-O Mixed Metal Oxides for the Effective Oxidative Dehydrogenation of Ethane to Ethylene – Effect of Promoting Metal Me. J. Cat. 270, 67-75 (2010).
Zhu, H., et al. Nb Effect in the Nickel Oxide-Catalyzed Low-Temperature Oxidative Dehydrogenation of Ethane. J. Cat. 285, 292-303 (2012).
Sadovskaya, E. M., et al. Mixed Spinel-type Ni-Co-Mn Oxides: Synthesis, Structure and Catalytic Properties. Catal. Sustain. Energy. 3, 25-31 (2016).
Alvarez, J., et al. Ni-Nb-Based Mixed Oxides Precursors for the Dry Reforming of Methane. Top. Catal. 54, 170-178 (2011).
Jin, S., Guan, W., Tsang, C. -. W., Yan, D. Y. S., Chan, C. -. Y., Liang, C. Enhanced hydroconversion of lignin-derived oxygen-containing compounds over bulk nickel catalysts though Nb2O5 modification. Catal. Lett. 147, 2215-2224 (2017).
Taghavinezhad, P., Haghighi, M., Alizadeh, R. CO2/O2-oxidative dehydrogenation of ethane to ethylene over highly dispersed vanadium oxide on MgO-promoted sulfated-zirconia nanocatalyst: Effect of sulfation on catalytic properties and performance. Korean J. Chem. Eng. 34 (5), 1346-1357 (2017).
Muralidharan, G., Subramanian, L., Nallamuthu, S. K., Santhanam, V., Kumar, S. Effect of Reagent Addition Rate and Temperature on Synthesis of Gold Nanoparticles in Microemulsion Route. Ind. Eng. Chem. Res. 50 (14), 8786-8791 (2011).
Sosa, Y. D., Rabelero, M., Treviño, M. E., Saade, H., López, R. G. High-Yield Synthesis of Silver Nanoparticles by Precipitation in a High-Aqueous Phase Content Reverse Microemulsion. J. Nanomater. , 1-6 (2010).
Morterra, C., Cerrato, G., Pinna, F. Infrared spectroscopic study of surface species and of CO adsorption: a probe for the surface characterization of sulfated zirconia catalysts. Spectrochim. Acta. A Molecul. Biomolecul. Spectrosc. 55, 95-107 (1998).
Yang, F., Wang, Q., Yan, J., Fang, J., Zhao, J., Shen, W. Preparation of High Pore Volume Pseudoboehmite Doped with Transition Metal Ions through Direct Precipitation Method. Ind. Eng. Chem. Res. 51 (47), 15386-15392 (2012).
Saleh, R., Djaja, N. F. Transition-metal-doped ZnO nanoparticles: Synthesis, characterization and photocatalytic activity under UV light. Spectrochim. Acta. A Molecul. Biomolecul. Spectrosc. 130, 581-590 (2014).
Ertis, I. F., Boz, I. Synthesis and Characterization of Metal-Doped (Ni, Co, Ce, Sb) CdS Catalysts and Their Use in Methylene Blue Degradation under Visible Light Irradiation. Modern Research in Catalysis. 6, 1-14 (2017).
Jin, S., et al. Cleavage of Lignin-Derived 4-O-5 Aryl Ethers over Nickel Nanoparticles Supported on Niobic Acid-Activated Carbon Composites. Ind. Eng. Chem. Res. 54 (8), 2302-2310 (2015).
Rojas, E., Delgado, J. J., Guerrero-Pérez, M. O., Bañares, M. A. Performance of NiO and Ni-Nb- O Active Phases during the Ethane Ammoxidation into Acetonitrile. Catal. Sci. Technol. 3 (12), 3173-3182 (2013).
Lee, S. -. H., et al. Raman Spectroscopic Studies of Ni-W Oxide Thin Films. Solid State Ionics. 140 (1), 135-139 (2001).
Mondal, A., Mukherjee, D., Adhikary, B., Ahmed, M. A. Cobalt nanoparticles as recyclable catalyst for aerobic oxidation of alcohols in liquid phase. J. Nanopart. Res. 18 (5), 1-12 (2016).
Wang, K., Yang, L., Zhao, W., Cao, L., Sun, Z., Zhang, F. A facile synthesis of copper nanoparticles supported on an ordered mesoporous polymer as an efficient and stable catalyst for solvent-free sonogashira coupling Reactions. Green Chem. 19, 1949-1957 (2017).
Song, Y., et al. High-Selectivity Electrochemical Conversion of CO2 to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode. Chemistry Select. 1, 6055-6061 (2016).

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