Journal
/
Química
/
分离游离卡本内斯、其混合二聚体和有机自由基
JoVE Journal
Química
É necessária uma assinatura da JoVE para visualizar este conteúdo.  Faça login ou comece sua avaliação gratuita.
JoVE Journal Química
Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
Please note that all translations are automatically generated. Click here for the English version.

分离游离卡本内斯、其混合二聚体和有机自由基

10,321 Views

•

10:44 min

•

April 19, 2019

DOI:

10.3791/59389-v

DOI:
10.3791/59389-v

•

10:44 min
April 19, 2019

•

4 Views
, ,
1Department of Chemistry and Pharmacy,Friedrich-Alexander-Universität Erlangen-Nürnberg

Summary

Automatically generated

我们提出了分离稳定的杂环卡本的方案。利用滤器插管和施伦克技术, 研究了一种循环 (烷基) (氨基) 卡本 (caac) 和n-杂环卡本 (nhc) 的合成方法。此外, 我们还提出了合成相关的氧敏感, 富含电子的混合 "Wanzlick 二聚体" 和减少稳定的有机自由基。

Explore More Videos

Schlenk LineAir-sensitive CompoundsCarbenesDimersFree RadicalsFilter CannulaDry And Degassed SolventsIminium SaltKHMDSDinitrogenDiethyl EtherIsopropanol Slush BathPotassium Tetrafluoroborate

Read Article

Cite this Article

Grünwald, A., Goodner, S. J., Munz, D. Isolating Free Carbenes, their Mixed Dimers and Organic Radicals. J. Vis. Exp. (146), e59389, doi:10.3791/59389 (2019).

Download .ris file

Copy

Share Video

.

Copy