In the titration of chloride with silver nitrate, the initial silver ion concentration is low due to the limited redissolution of the sparingly soluble silver chloride precipitate. Chloride is completely consumed at the equivalence point, and the silver concentration rises sharply. Beyond the equivalence point, the high silver concentration is primarily from the excess titrant. The shape of the titration curve is influenced by the solubility product of the precipitate. The lower silver iodide solubility product suggests a lower silver concentration and a larger break at the equivalence point. The larger silver chloride solubility product suggests a higher silver concentration and a smaller break at the equivalence point. When a mixture of iodide and chloride is titrated against silver nitrate, silver iodide precipitates first due to its low solubility product. Close to the first equivalence point, as iodide gets nearly completely consumed, the silver concentration increases until the solubility product of silver chloride is reached. Once all the chloride precipitates, a second equivalence point is observed, and the silver concentration rises again.