Prova di trazione di materiali polimerici fibrorinforzati (articolo)

Prova di trazione di materiali polimerici fibrorinforzati

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Structural Engineering

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JoVE Educazione Scientific Structural Engineering

Tension Test of Fiber-Reinforced Polymeric Materials

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08:42 min

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April 30, 2023

Panoramica

Source: Roberto Leon, Department of Civil and Environmental Engineering, Virginia Tech, Blacksburg, VA

Fiber-reinforced polymeric materials (FRP) are composite materials that are formed by longitudinal fibers embedded in a polymeric resin, thereby creating a polymer matrix with aligned fibers along one or more directions. In its simplest form, the fibers in FRP materials are aligned in an orderly, parallel fashion, thus imparting orthotropic material characteristics, meaning that the material will behave differently in the two directions. Parallel to the fibers, the material will be very strong and/or stiff, whereas perpendicular to the fibers will be very weak, as the strength can only be attributed to the resin instead of the whole matrix.

An example of this unidirectional configuration is the commercially available FRP reinforcing bars, which mimic the conventional steel bars used in reinforced concrete construction. FRP materials are used both as stand-alone structures such as pedestrian bridges and staircases, and also as materials to strengthen and repair existing structures. The thin, long plates are often epoxied to existing concrete structures to add strength. In this case, the FRP bars act as external reinforcement. The FRP bars and plates are lighter and more corrosion resistant, so they are finding applications in bridge decks and parking garages, where de-icing slats lead to rapid deterioration of conventional bars.

In this laboratory exercise, the tensile behavior of a unidirectional specimen will be studied, with emphasis on its ultimate strength and deformation capacity. The behavior of the specimen is expected to be elastic until failure, which is expected to occur in a sudden and explosive manner. This behavior should be contrasted with those of ductile steels, which exhibit extensive deformation capacity and strain hardening before failure.

Principi

The strength of the FRP material is directly related to the strength of the individual fibers and the amount of fibers that can be put into a unit volume. Theoretically, one can achieve as high as 90% fibers by volume; however, this high a density of fibers cannot be achieved through economically viable commercial fabrication processes. Typically, most FRP material applications in civil engineering have around 50-60% fibers by volume.

There are several types of FRP materials based on different classes of fibers, such as glass fiber-reinforced polymers (GFRP), carbon fiber-reinforced polymers (CFRP), and aramid fiber-reinforced polymers (AFRP). Aramids are a class of synthetic polymers, similar to nylon, that exhibit extraordinary strength and resistance to temperature change. Table 1 shows the variety of different characteristics of each class of fibers. Care must be exercised when evaluating the suitability of FRP materials for a particular application in order to match base material and FRP properties, such as ensuring complementary thermal coefficients of expansion to ensure proper long-term behavior. In addition, one must confirm that there is a lack of chemical interaction between the FRP and base material, as many fibers and resins are sensitive to corrosion, moisture, and high temperature in both fabrication and use.

Characteristic	Glass Fibers	Carbon Fibers	Aramid Fibers
Strength	High	Very high	High
Stiffness	Low	Very high
Thermally Stable	<1500ºF	<3500ºF	± 350ºF
Impact Resistance	Low	Low	High
Moisture Resistance	Sensitive	Highly Resistant	Sensitive
Chemical Resistance	Sensitive	Highly Resistant	Highly Resistant
Conductivity	Highly insulating	High conductivity	Low conductivity
Price	$	$$$	$$

Table 1. FRP material properties.

Beyond the simplest uniaxial application in rebars, there are many applications that utilize stacks of uniaxial fibers in either specific or random directions to create laminate materials.

In most cases, these plates are still orthotropic, but now with two strong directions and one weak direction (out of the plane). In the assembly of these structures, there are three important definitions to consider. A ply is a single layer of fiber mat or single pre-preg sheet. A pre-preg sheet is a fiber mat impregnated with resin, pre-cured under heat, pressure, or both, and intended for field applications where, for example, the sheet will be glued to an existing surface to strengthen it. A laminate is a cured stack of several plies. Notice that a laminate can be made up of plies with different fibers or fiber volumes, leading to easy customization of the FRP for its intended use. Laminates are used where the FRP can be applied to a smooth surface and only partial coverage is needed; plies and pre-preg sheets are used when wrapping entire structural elements and where the surface is uneven.

When creating laminates, pressure needs to be applied to squeeze out as much resin as possible in order to increase the fiber volume. Some common resins used in FRP materials include epoxies, vinylesters, and polyesters. The principal function of resins is to transfer stress between adjoining fibers in the matrix and to protect the fibers from both mechanical and environmental damage. Polymer resins are generally petrochemical or natural gas derivatives and can either be thermosets or thermoplastics. While thermosets cannot be deformed upon curing, thermoplastics, such as polyesters and vinyl esters, are deformed and crosslinked upon curing, thereby imparting greater thermal resistance. Both types of polymers can be used in composite materials and can benefit in combination with reinforcing fibers. However, the majority of thermoplastic polymers are not used in composite form, as they already exhibit high strength, whereas thermosetting polymers generally require high fiber volumes of strong fibers in order to achieve the same strength. Thermosets are the dominant polymer in the current composite industry, as the wide variety of polymers available can satisfy virtually every conceivable end use application. The polymer resins are selected and tailored for each individual application, strongly based on the physical and mechanical properties of the product and the fabrication process requirements.

In addition to the reinforcing fibers and resins, there are also fillers and additives that play an important role in the composite system. Fillers and additives are processing aides that impart "special" properties to tailor the end product to the desired specification. Fillers or extenders are used in many composites material systems and have three primary functions:

To improve certain mechanical properties, such as compressive strength, fire resistance, crack propagation, and chemical resistance.
To improve processability of the composites system, such as uniformity of physical features and surface finish.
To reduce material cost by replacing some of the more expensive polymer and reinforcement in the system.

Some common fillers include calcium carbonate, clay, talc, silica, mica, and microspheres; however, the most common filler is calcium carbonate because of its low cost and availability.

On the other hand, additives cover a wide variety of different materials that are used in relatively small quantities, but nevertheless play an integral role in the processing and end product performance of the composite. Additives play a myriad of roles, such as:

To modify the cure rate.
To extend shelf life and prevent shrinkage.
To improve weatherability and reduce viscosity.
To add color and reduce porosity.

Some common additives include catalysts and promoters, used to affect the cure of thermoset polymers, inhibitors, to control the thermoset reaction, release agents, to allow parts to be more easily removed from their mold, as well as pigments, UV absorbers, and fire retardants.

When considering the entire FRP material system (fibers, resin, fillers, and additives), the principal factors affecting the mechanical properties of FRP are the type of fiber reinforcement, fiber volume, fiber orientation, resin type, manufacturing process, and quality control.

For the three main classes of fibers used in FRPs – carbon, aramid and glass- the stress-strain behavior to failure is essentially linearly elastic, and the fibers have very low strain capacity. This characteristic results in sudden failures, without any evidence of ductility.

When modeling fiber and matrix behavior, either the strain capacity of the resin or the fiber can govern the mechanical behavior. In practice, the material will be very heterogeneous at the small scale between the fiber and matrix; however, for modeling and design purposes, we consider it homogeneous with an equivalent modulus of elasticity based upon the rule of mixtures. The rule of mixtures dictates that the various properties of composite materials will be the result of the weighted mean from the constituent parts, either in parallel or in series. Before the cracking of fiber in FRP materials or before the cracking of matrix in FRC, the composite material will behave according to the rule of mixtures:

σ_c= σ_mV_m+ Ση_fiσ_fiV_fi
V_m + ΣV_fi = 1

σ_c= strength of the composite
V_m= volume fraction of the fibers
σ_m = strength of the matrix
V_m = volume fraction of the matrix
σ_fi = strength of the fibers

where,
N_f= 0.375, for random fibers
N_f= 1, for unidirectional fiber stressed in fiber direction
N_f= 0, for unidirectional fiber stressed perpendicular to the fiber direction

A similar equation can be used for calculating the modulus of elasticity (E_c) of a composite. Consider a woven hybrid composite fabric composed of aramid fibers (s_f1 = 500,000 psi, E_f1 = 50×10⁶ psi) and carbon fibers (s_f2 = 300,000 psi and, E_f2 = 15×10⁶ psi) in an epoxy matrix (s_m = 8,000 psi and E_m = 0.50×10⁶ psi). In this fabric, the carbon fibers run in the 0^o direction, and the aramid fibers run in the 90^o direction. The total fiber volume fraction is 0.60, with an equal volume of carbon and aramid fiber. The strengths and modulus in the two perpendicular directions are:

s_c,0°= s_mV_m+ S h_fis_fiV_fi = (8)(0.4)+(300)(0.6) = 183.2 ksi = s₁

s_c,90°= s_mV_m+ S h_fis_fiV_fi = (8)(0.4)+(500)(0.6) = 303.2 ksi = s₂

E_c,0°= E_mV_m+ S h_fiE_fiV_fi= (0.5)(0.4) + (50)(0.6)= 30.2 x 10⁶ ksi = E₁

E_c,90° = E_mV_m+ S h_fiE_fiV_fi= (0.5)(0.4) + (15)(0.6)= 9.2 x 10⁶ ksi = E₂

Additionally, when designing FRP materials, the fibers must be long enough to break, but not pull out of the material. For most common applications, fibers are more than long enough, but nonetheless must be considered a design requisite.

To demonstrate and contrast the stress-strain behavior of two types of FRP, a relatively weak glass FRP and a strong carbon FRP, simple tension tests will be conducted as described next. An important issue in testing these materials is that the soft matrix can be easily damaged by the hard metal grips, leading to failures just outside the grips. Tests that fail in this manner are generally not considered to produce valid results. A simple procedure that has given satisfactory results is described below.

Procedura

Take proper safety precautions, and wear eye protection because the explosive failure typical of these specimens sends many small, sharp shards flying.
Obtain four FRP specimens. Two will be from a unidirectional 0.5-inch E-glass FRP plate cut into 1" x 8" specimens, one along the direction of the fibers and one perpendicular to the fibers. The third specimens will be a 0.25-inch carbon FRP rebar, and the fourth will be a 0.25 FRP E-glass rebar. The rebar specimens should be about 24 inches long.
Attach holders for the instrument by embedding 12 in. of the ends of the specimens into slightly larger steel round and rectangular sections and infill the empty spaces with high-strength epoxy. Let the epoxy cure as per manufacture's specifications. This type of end connection is needed because the serrations in conventional UTM grips will destroy the resin and lead to premature end failures.
Proceed in the same manner as the other tension tests by turning on the UTM and initializing its software.
Insert the specimens into the grips and tighten them.
Load the specimens in deflection control at a rate of about 0.2 in. per minute.
If an extensometer is used to measure Young's modulus, make sure to demount it at a strain of 0.01.
As the specimen begins to fail, popping sounds and small shards will begin to fall off the specimen, followed by an explosive failure of the material, which separates into a fibrous flower-like structure.

Fiber-reinforced polymeric materials, FRP, are composite materials that are formed by embedding fibers in a polymeric resin, creating a matrix that is very strong in the direction of the fibers.

In their simplest form, fibers in FRP materials are aligned orderly in one direction, and encased in resin, causing the material to behave orthotropically. Mechanical properties of these materials are very different in the direction of the fibers compared to the other two principle directions.

An FPR material is very strong in the direction of the fibers because of the high strength of the fiber, behaving elastically until the fibers fracture, and the material fails in an explosive manner. The material is, however, very weak in the perpendicular direction because of the very much lower strength of the resin.

In this video, the tensile behavior of a unidirectional specimen will be studied, with emphasis on its ultimate strength and deformation capacity.

The strength of FRP materials is directly related to the strength of the individual fibers. As the percentage of fibers in a material increase, the strength of the material increases. Typical materials have approximately 50% fibers by volume.

The unidirectional strength of FRP is often used in reinforcing bars, or rebars, but can be realized in more than one direction of the material by controlling the direction of the fibers.

Fibers can be places in random directions, or single plys of uniaxial layers can be place in alternating directions, resulting in two strong directions and one weak direction. The fiber and resin used to make an FRP must be chosen to be compatible with each other and meet application requirements.

The class of the fiber used, typically glass, aramid, or carbon, affects the properties and cost of the final product. In general, the fibers have very low strain capacity, resulting in sudden failures without any evidence of ductility.

The resin primary acts to transfer stress and protect fibers from mechanical and environmental damage. During manufacturing, pressure is applied to squeeze out as much resin as possible to increase the strength of the material. It is important to note that the individual fiber properties are not the properties of the composite. Instead, according to the rule of mixtures, properties of the composite are a result of the weight and mean of the constituent parts.

In the next section, we will conduct simple tension tests on a Universal Testing Machine to compare the stress/strain behavior of glass and carbon FRP, while taking care to properly prepare the samples to obtain valid results.

Obtain four FRP specimens. Two will be from a unidirectional 0.5 inch E-glass FRP plate cut into one-by-eight inch specimens: one along the direction of the fibers, and one perpendicular to the fibers. The third specimen will be a 0.25 inch carbon FRP rebar, and the fourth will be a 0.25 glass FRP rebar. The rebar specimens should be about 24 inches long.

Prepare the FRP rebar specimens in advance by embedding 12 inches of the ends in slightly larger steel round and rectangular sections and filling the empty spaces with high strength epoxy. Allow several days for curing, according to the epoxy specifications.

This type of end connection is needed because the serrations in conventional UTM grips will destroy the resin and lead to premature end failures. Proceed in the same manner as the other tension tests, by turning on the UTM and initializing its software. Then, insert a specimen into the grips, and lock it in place.

Load the specimen in displacement control at a rate of about 0.2 inches per minute. As the specimen begins to fail, popping sounds will be heard and small shards will begin to fall off the specimen. Followed by an explosive failure of the material, which separates into a fibrous flower-like structure.

Here is the stress/strain curve for the E-glass FRP plate specimen being loaded in the direction of the fibers. From this graph, we can determine the maximum force, tensile strength, and strain and calculate the modulus of elasticity. These results are reasonable for a material specified at 50% E-glass fiber volume showing essentially liner behavior.

This graph shows the same material loaded perpendicular to the direction of the fibers. We can see a decrease in the maximum force, tensile strength, strain, and the modulus of elasticity. Note that a significant amount of the strength measured in this particular specimen comes from the fibers in the outside protective layers, in which the fibers are randomly oriented. The very large difference between the two directions emphasizes the tailorability of the material properties. In this case, we have a material that is strong in one direction, and weak in the other.

The failure surfaces bear witness to this, with the one for the fibers aligned longitudinally showing numerous broken fibers, and the one with the fibers aligned perpendicularly showing the typical surface for a resin failure at an interface. Comparing the behavior of the FRP rebars, there is a very significant difference in strength and modulus of elasticity. Both materials fail immediately after carrying their maximum load.

The difference between the strong carbon FRP bar, and the softer, but far more ductile E-glass one, is obvious in this linearized graph. However, there is little ductility, as they fail at a fraction of the strain of metals such as a36 steel.

FRP materials are used in a myriad of civil engineering applications, including original construction and repair applications. Let’s look at a couple of common uses of FRPs.

FRP sheets, laminates, and bars can be impregnated with resin and precured for use in field applications. The FRP bars and plates are light and corrosion resistant, so they’re finding applications in bridge decks and parking garages, where deicing leads to rapid deterioration of conventional bars.

Many marine applications also use FRP materials for their resistance to corrosion and salt. FRP is used extensively in the boating industry, as well as for naval structures and pipelines.

You’ve just watched JoVE’s introduction to tension testing of fiber-reinforced polymeric materials, or FRPs. You should now understand the components of FRPs and standard laboratory testing for determining their strength.

Thanks for watching!

Risultati

Typical stress-strain curves for the E-glass FRP plate specimens are shown for the plate with the two uniaxial layers aligned longitudinally (Fig. 1) and respectively perpendicularly (Fig. 2) to the direction of loading. For the case of the load applied parallel to the fibers (Fig. 1), the maximum force was 12.32 kips, corresponding to a tensile strength of 98.6 ksi. The failure occurred at a strain of 2.98% and the modulus of elasticity, calculated from a line tangent at 30% of the ultimate load, was 5686 ksi. Since an extensometer was not used, this value should be taken only as indicative of the Young's modulus. The behavior is essentially linear to failure. The results are reasonable for a material specified at 50% E-glass fiber volume.

Figure 1: Stress-strain curves for the E-glass FRP plate: load applied parallel with the fibers.

For the case of the load applied perpendicular to the fibers (Fig. 2), the maximum force was 2.72 kips, corresponding to a tensile strength of 10.9 ksi. The failure occurred at a strain of 2.24 and the modulus of elasticity, calculated from a line tangent at 30% of the ultimate load, was 640 ksi.

Figure 2: Stress-strain curves for the E-glass FRP plate: load applied perpendicular to the fibers.

As expected, there was a very large difference between the two directions as shown in the comparison graph (Fig. 3). This emphasizes the tailorability of the material properties; in this case we have a material that is strong in one direction and weak in the other.

Figure 3: Stress-strain curves for the E-glass FRP plate: load applied parallel (blue) and respectively, perpendicular (orange) to the fibers.

The failure surfaces bear witness to this, with the one for the fibers aligned longitudinally showing numerous broken fibers and the one with the fibers aligned perpendicularly showing the typical surface for a resin failure at an interface.

The plot in Fig. 4 shows a comparison of the behavior of the FRP rebars. There is a very significant drop in strength (a factor of about 2) and modulus of elasticity (about a factor of 4) decrease when we compare the carbon FRP and the E-glass FRP curves. All of these FRP materials can be seen to have very little or no ductility, failing immediately after carrying their maximum load.

Figure 4: Linearized stress-strain curves for E-glass (orange) and respectively, carbon (blue) FRP rebars.

Applications and Summary

FRP materials are light, strong composites used extensively in both civil, mechanical, and aerospace applications. They are made up of strong fibers embedded in a resin or similar matrix, and they are manufactured in many forms, including prepeg strips and laminates. Their strength and stiffness can be tailored by varying the amounts, types, and directionality of the fibers. FRP materials have a much smaller deformation capacity than metals or polymers and give little warning of failure, thus are important to study the manner and mechanics of failure.

FRP materials are used in a myriad of civil engineering applications from transportation to construction materials, marine to electronic applications, and even consumer products to business equipment. There are GFRP poles and towers for hanging power and telephone lines, FRP stairwells and parking garages, FRP roofing, seawall reinforcement, FRP marine fenders, and ground anchorage to name a few. They are also extensively used to strengthen and repair structures.

Many highway structures, such as the Prodeck Bridge System and Auto Skyway, employ FRP materials to help reinforce and support the loads that traverse the bridge in the road systems. Even the guardrails that one sees on the sides of the highways can be built using FRP materials. FRP materials are also used to transport people over pedestrian bridges, such as the Aber Feldy Golf Club Bridge in Scotland and the Shank Castle footbridge in Cumbria, U.K.

Many marine applications use FRP materials for their resistance to corrosion and salt. FRP is used extensively in the boating industry, as well as for naval structures and pipelines. FRP materials are not only seen in practical construction applications, but also in fun applications, such as in artistic architectural forms and roller coasters. The shooting arrow sculpture in San Francisco, named “Cupid’s Span”, is made from FRP materials, as are the pedestals in many roller coasters in Six Flags nationwide.

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