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二碘化钐的制备和使用(SMI<sub> 2</sub>)在有机合成中:HMPA和镍(II)盐的钐巴尔比耶反应的机理作用
JoVE Revista
Quimica
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JoVE Revista Quimica
Preparation and Use of Samarium Diiodide (SmI2) in Organic Synthesis: The Mechanistic Role of HMPA and Ni(II) Salts in the Samarium Barbier Reaction

二碘化钐的制备和使用(SMI<sub> 2</sub>)在有机合成中:HMPA和镍(II)盐的钐巴尔比耶反应的机理作用

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12:22 min

February 04, 2013

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12:22 min
February 04, 2013

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Summary

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二碘化钐(SMI编制一个简单的过程,<sub> 2</sub>)在THF中进行说明。的作用的两个主要的添加剂,即六甲基磷酰胺(HMPA)和Ni(乙酰丙酮)<sub> 2</sub在SM介导的反应是体现在的Sm-巴比尔反应。

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