Resonance Raman Spectroscopy of Extreme Nanowires and Other 1D Systems

David C. Smith; Joseph H. Spencer; Jeremy Sloan; Liam P. McDonnell; Harrison Trewhitt; Reza J. Kashtiban; Eric Faulques

doi:10.3791/53434

JoVE Journal > Engineering

Ingeniería

Resonance Raman Spectroscopy of Extreme Nanowires and Other 1D Systems

Published: April 28, 2016

doi:

10.3791/53434

David C. Smith¹, Joseph H. Spencer¹, Jeremy Sloan², Liam P. McDonnell¹, Harrison Trewhitt², Reza J. Kashtiban², Eric Faulques³

¹School of Physics and Astronomy,University of Southampton, ²Department of Physics,University of Warwick, ³Institut des Matériaux Jean Rouxel,University of Nantes CNRS

Summary

The paper describes a method for producing extreme nanowires by melt infiltration into carbon nanotubes and how 1D systems may be characterized and investigated using Resonance Raman Spectroscopy to determine vibrational and optical excitation energies.

Abstract

This paper briefly describes how nanowires with diameters corresponding to 1 to 5 atoms can be produced by melting a range of inorganic solids in the presence of carbon nanotubes. These nanowires are extreme in the sense that they are the limit of miniaturization of nanowires and their behavior is not always a simple extrapolation of the behavior of larger nanowires as their diameter decreases. The paper then describes the methods required to obtain Raman spectra from extreme nanowires and the fact that due to the van Hove singularities that 1D systems exhibit in their optical density of states, that determining the correct choice of photon excitation energy is critical. It describes the techniques required to determine the photon energy dependence of the resonances observed in Raman spectroscopy of 1D systems and in particular how to obtain measurements of Raman cross-sections with better than 8% noise and measure the variation in the resonance as a function of sample temperature. The paper describes the importance of ensuring that the Raman scattering is linearly proportional to the intensity of the laser excitation intensity. It also describes how to use the polarization dependence of the Raman scattering to separate Raman scattering of the encapsulated 1D systems from those of other extraneous components in any sample.

Introduction

Raman spectroscopy and Resonance Raman spectroscopy are well-established techniques that are widely exploited scientifically and technologically. Whilst first reported by Raman himself in 1928¹ the key to wide spread use of Raman spectroscopy was the development of lasers, tunable lasers in the case of Resonance Raman, to provide high intensity, narrow bandwidth excitation sources. This paper sets out why Resonance Raman scattering is a particularly important method for investigating the fundamental physics and characterizing samples of 1D systems in general and extreme nanowires, e.g. nanowires with diameters of ~1-5 atoms. It also discusses difficulties particular to Raman spectroscopy of such nanowires and a protocol that allows these to be overcome and thereby achieve high repeatability measurements of the laser energy dependence of the Raman scattering efficiency in these systems.

There is a wide range of extended, crystalline 1D quantum systems, also known as nanowires, available for study and application. These include vapor-liquid-solid grown semiconductor nanowires², lithographically defined nanowires³, anodic alumina and track etch membrane template nanowires⁴ and others. A key reason for the interest in these systems is that they combine large quantum confinement effects with the ability for electrons and other excitations to move freely along the structure. In some respects nanowires are quite different from their parent material, e.g. reduced electromagnetic screening due to free charges⁵, and in some cases reduced electron scattering leading to ballistic transport⁶. However, in many respects the nanowires are still bulk like, e.g. the local bonding and crystal structure, and nearly always the fundamental quality of the electronic wave functions at the atomic scale are only weakly modified compared with bulk so that the envelope approximation⁷ is valid. However as the dimensions of the confined directions are reduced to a few atoms, nanowires with entirely new bonding can occur forming never previously seen allotropes^8-10. These nanowires are extreme in two senses; they are at the extreme limit of the possible reduction in cross-section^11-13 and they have extreme properties^10,13,14.

Before undertaking Resonance Raman spectroscopy, it is necessary to produce the extreme nanowire samples. The methodology set out in this paper for generating these nanowires is the melt infiltration of materials into single walled carbon nanotubes. Melt infiltration is one of two-high yield filling protocols used for obtaining continuously filled single-walled carbon nanotubes (SWNT), the other being sublimation, which is popular for the introduction of some molecules (i.e. fullerenes) and some binary salts, most recently CsI¹³. While the latter method produces near quantitative filling, it is limited in that the material to be introduced must readily sublime which greatly constrains the number and type of fillings that may be introduced into SWNT. The melt infiltration filling protocol can, with care, be used to produce near quantitative filling¹⁵ and has fewer constraints than that of the sublimation protocol. These are that the material must have a surface tension lower than 100-200 mN m^-1 and a melt temperature below about 1,300 K to avoid damaging the host SWNTs.¹⁶

Transmission electron microscopy (TEM) is the best method to characterize the quality of the filling of the carbon nanotubes and identify the crystalline structure or structures of the extreme nanowires produced. Solving structures of SWNT-embedded crystal fragments from HRTEM images involves trial-and-error comparisons between image simulations from trial crystal fragment models and the experimentally obtained image contrast. This paper describes a protocol for confirming the microstructure of the extreme nanowire motifs in SWNT samples by HRTEM image simulation as a prelude to their spectroscopic characterization.

Resonance Raman spectroscopy¹⁷ is an ideal tool both for understanding the fundamental physics of extreme nanowires and, once the resonance energies have been determined, for characterizing the type and quality of samples of nanowires. Fundamentally, Resonance Raman allows the direct determination of both optical and vibrational excitation energies¹⁷. With additional modeling of the photon energy dependence of the resonance it is possible to quantify the electron-phonon interaction¹⁷. Once resonant energies have been determined for particular extreme nanowires, the Raman spectrum of the nanowires can be used to track strain¹⁸ and structural phase changes¹⁹ due to temperature, hydrostatic pressure, or bending of the wire. Whilst it still to be proven, it is likely that in some magnetic extreme nanowires spin excitations will lead to Raman scattering allowing them to be probed. Extension of Raman scattering to samples held in a spectroelectrochemical cell can be used to probe charge transfer between extreme nanowires and host nanotubes²⁰. As a characterization tool Raman spectroscopy provides a method for non-contact, non-destructive determination of nanowire type and quality²¹. It can be used as a tool for characterizing samples after production and/or purification and even when the nanowires have been included in devices such as transistors or composites which are at least partially transparent at the necessary photon energies.

There is no one technique that can provide a direct alternative for Resonance Raman scattering (RRS); however there are a range of other techniques that overlap some aspects of the capabilities this method. In terms of determining the optical transition energies of extreme nanowires UV-VIS-NIR absorption measurements²² offer a much simpler technique. However in samples with an ensemble of different structures absorption spectroscopy cannot separate the different optical features into sets associated with particular structures. Resonance Raman scattering can achieve this due to the association of optical and vibrational spectra. A combination of the two techniques in which a UV-VIS-NIR absorption measurement highlights target energies of Resonance Raman can speed up the overall process considerably. Photoluminescence excitation spectroscopy (PLE)²³ does offer the ability to associate different optical transitions in a single sample; however it only works for some, particularly non-metallic nanowires, and it is only slightly less complicated to perform than RRS and in general requires mono-dispersed samples protected from the environment to be completely successful. Unlike PLE, Resonance Raman spectroscopy works equally well with bundled and mono-dispersed samples and therefore requires little sample preparation. Whilst as yet little used, Rayleigh scattering spectroscopy on individual nanowires²⁴ followed by Transmission Electron Microscope (TEM) analysis of the structure of the nanowire can identify all of the optical excitation energies of the wire in the spectral range investigated and identify a particular nanowire structure. However, this technique does not provide the vibrational energy information possible with RRS; it is very challenging to perform and is never going to be suitable as a general characterization tool. In terms of the vibrational energy information the only currently viable alternative is IR spectroscopy²⁵ however this is likely, due to selection rules, to probe a different set of vibrational energies and thus be complementary rather than competitive. In addition IR spectroscopy will suffer from the same issues with ensemble samples as UV-VIS-NIR absorption measurements.

As already discussed Raman spectroscopy has been applied to a wide range of problems within science. In molecular systems it is used to complement IR spectroscopy for determining vibrational spectra and also as a fingerprinting technique for analyzing the composition of materials. It has been widely exploited in crystalline systems, e.g., the Light Scattering in Solids series of books includes nine volumes. In the case of 3D and 2D systems, resonant excitation is used less for enhancing the overall scattering intensity and more for enhancing the contribution of specific optical transitions within the Raman process leading to the breakdown of the standard selection rules and the ability to quantify the interaction of the excitations observed in the Raman spectrum with specific electronic states. More recently Raman spectroscopy has been central to the study of carbon nanotubes, particularly single walled carbon nanotubes. The carbon nanotube research²¹ has highlighted the fact that for 1D systems resonant excitation is not optional, as it is for most applications of Raman for 3D and 3D systems, but is strictly necessary. This is because non-resonant Raman scattering is too weak to be observed and it is only when the excitation is resonant with the strong van Hove singularities in the optical density of states, that are a feature of 1D systems in particular, that any Raman spectrum can be observed. Thus in the case of extreme nanowires the use of Raman spectroscopy requires a full Resonance Raman measurement to find the resonances of all of the nanowires in a sample before Raman spectroscopy can be applied to studying these materials.

Protocol

1. Sample Preparation: Melt Filling of SWNTs with Mercury Telluride (HgTe) and Other Materials

Caution: Some chemicals used in this protocol can be hazardous to health. Please consult relevant material safety data sheets before any chemistry takes place. Utilize appropriate personal protective equipment (lab coat, safety glasses, etc.) and engineering controls (e.g., glove box, fume hood etc.) when handling carbon nanotubes and mercury telluride.

Preheat ~50 mg SWNTs to 400 °C in dry air or 500 °C in vacuo.
NOTE: If dry air is used, there may be some loss of volume of the SWNTs, typically 20-40%. Preheating of SWNTs prior to filling in this way has been reported to improve the proportion of SWNTs filled with molecules or crystals¹².
In an Argon glove box grind ~20 mg of the preheated SWNTs²⁶ with an equal volume of the filling material (in this case mercury telluride) for >20 min using an agate mortar and pestle, applying force to produce an intimate mixture.
While still in the glove box, transfer the whole amount of the SWNT/filling material mixture to an 8-10 mm (internal diameter), 6-10 cm long silica quartz ampoule sealed at one end and open at the other.
NOTE: A filter paper funnel is useful in 1.3. Do not use ordinary lab glass ampoules as this grade of glass may melt and damage the furnace.
Inside the glove box temporarily seal the open end of the ampoule with plastic film for transfer to the vacuum line. Remove the film once it is secured to a vacuum line.

2. Evacuation and Filling Step

Seal the ampoule containing the SWNT/filling composite under moderate vacuum (typically ~0.1 Pa).
In a programmable tube or muffle furnace, heat the sealed ampoules at a ramp rate of ~5 °C min^-1 to ~100 °C >melting point (m.p.) of the filling with thermal cycling at temperatures of +/- 100 °C for 12 hr periods for a total time of 48 hr.
Cool the ampoule in the furnace to room temperature at a rate no greater than 5 °C min^-1 prior to breaking open and storage.
Hazard: Breaking open ampoules can potentially cause cuts or can implode, presenting a significant eye impact hazard. Eye protection and safety gloves should be worn during this operation. Ampoules may be safely broken by first scoring the ampoule in the center with a glass scribe and then breaking at this position by wrapping in a stiff cloth and then simultaneously applying bending pressure either side of the score point.

3. Sample Cleaning

Remove exterior compounds to the SWNTs by gently refluxing the sample in a 1:1 mixture of concentrated HCl and HNO₃ (total volume 50 ml) for ~1 hr.
Wash the sample with de-ionized water and filter using a controlled pore filter that has a pore size of ~0.22 µm.

4. Analysis of the Sample by High Resolution TEM (HRTEM)

Disperse ~ 5 mg of sample in ~5 ml of ethanol with sonication at about 20% of 750 W of power in a tip sonicator with 2 sec on/off pulsing.
Place 1-2 drops of the dispersion onto 3.05 mm lacey carbon coated HRTEM specimen grids.
Perform HRTEM^27,29 imaging in an 80 kV aberration-corrected HRTEM and equipped with a 4,008 x 2,672 pixel charge-coupled device (CCD).
Precalibrate the CCD at the same magnification to be used for imaging the nanowire/carbon nanotube composite using (111) lattice planes (separated by 0.235 nm) of dispersed Au nanoparticles.
Obtain images of discrete filled SWNT samples at a magnification of at least 600,000 times and under optimum Scherzer defocus imaging conditions.
Confirm the composition of the fillings by energy dispersive X-ray microanalysis (EDX)^28,29 ideally using the same HRTEM as used for imaging. Use a ~1 nm electron probe focused onto filled bundles of SWNTs.

5. Confirming the Microstructure of SWNT Embedded Extreme Nanowire by HRTEM Image Simulation

NOTE: For image simulations a standard multislice image simulation package such as SimulaTEM may be used which produces bitmap image (*.bmp) simulations that may be directly compared. For exact details on operation of software through various platforms, please follow manufacturer's protocol.

Choose a HRTEM image of a nanowire free of drift and with clearly resolved atom columns visible for a distance along the SWNT of ~5 nm. The long axis of the nanowire/nanotube composite should be orthogonal with respect to the electron beam.
Generate atomic coordinates by plotting atom positions directly onto atom columns using a calibrated image (step 4.4).⁸ in the case of a high crystal symmetry structure; a single image is required¹¹. Add 2-3 atomic layers in projection to the model to complete the structure. For a low symmetry model, resolve the crystal structure from two or more different projections of two or more crystallographically identical fragments in two separate nanotubes¹⁰.
Generate *.xyz nanotube coordinates for a nanotube of suitable diameter using a suitable program (e.g. TubeGen 3.4) determined according to the relation.

Where d is the diameter, a is the C-C bond distance (0.246 nm) and n and m the tube conformation. The nanotube should be large enough to accommodate the outside volume of the crystal generated from step 5.2 taking into account the van der Waals radius of the carbon atoms of the nanotube wall (0.17 nm).
Assemble composite atomic coordinates from the nanowire/nanotube composite using a suitable structure manipulation program (e.g. Crystalmaker) such that the 1D crystal is inserted into and aligned along the common central axis of the nanotube and then save the final model coordinates in *.xyx or *.pdb format.
Produce image simulations of nanowire/nanotube composite using a standard multislice simulation protocol (e.g. SimulaTEM) using the atomic coordinates generated in 5.3.
Simulate the composite in a preliminary orientation such that the long axis of the composite is orthogonal to the electron beam. Use simulation parameters consistent with the accelerating voltage (e.g. 80 kV) and a coefficient of spherical aberration (Cs; e.g. 0.001 mm) consistent with the HRTEM instrument.
Visually compare the appearance of the simulation to the image. If a good visual match is not obtained rotate the fragment about the long axis of the extreme nanowire/nanotube composite by a suitable interval (e.g. 10°) and then re-simulate. Repeat this step for a full 180° rotation of the composite.
If it is suspected that the experimentally imaged fragment is tilted with respect to an ideal orthogonal orientation, repeat steps 5.5 to 5.7 with a tilt of ±10° until a good match is obtained.

6. Preparation of Sample Suitable for Raman Spectroscopy

Hazard: The sonication of nanotube solutions may be able to form an aerosol containing tubes or filled tubes and if the samples are subsequently not handled correctly this could lead to the operator breathing in nanotubes or filled nanotubes.

Place 20 mg of nanotube product into a vial, add 20 ml ethanol and seal lid.
Place vial in bath sonicator and sonicate at 20 W for ~20 min until liquid turns dark. Leave for ~5 hr to allow nanotube aerosolized in vial to settle out.
Gently swirl vial to agitate bottom suspension if present.
Using a pipette, drop coat 10-20 µl of suspension onto oxide coated silicon substrate (5 mm x 10 mm) and allow ethanol to evaporate.

7. Mounting Sample in Cryostat

Place a droplet of metallic conductive paint (approximately 2 mm²) on the Cryostat cold finger and gently place silicon sample on paint droplet and let dry for ~2 hr.
Seal cryostat as per manufacturer's protocol and bolt Cryostat onto XYZ stage and pump Cryostat to 10^-6mbar using an oil free pump.

8. Initial Setup and Optimization of Raman System

NOTE: Please refer to the experimental schematic presented in Figure 10 before reading the following sections of the protocol.

Set incident wavelength to desired value (e.g. 800 nm) using a tunable laser source as per manufacturer's protocol.
Tune laser pre-filter (C in Figure 10) as per manufacturer's protocol to maximize transmission of laser power through filter. If using a Volume Bragg Grating (VBG) modify the optical set up in accordance with Figure 10 and use the following sub procedure.
1. Rotate VBG around vertical axis to reduce transmission of laser through the VBG. Fine tune using VBG mirror mount.
2. Position mirror into Bragg reflected beam and retroreflect beam back onto VBG. Adjust mirror to suppress transmission of the retroreflected beam through VBG.
3. Measure laser power transmitted through iris 1 and fine adjust VBG and retroreflecting mirror to maximize transmission of laser power.
Adjust the post-filter (C) mirrors (M1 and M2) to return laser beam to predefined path by repositioning reflections from relevant beam splitters (BP1 and BP2) onto the two beam observation cameras (C1 and C2).
Measure laser photon energy by indirectly scattering into spectrometer. Do not scatter light directly into the spectrometer as this can damage sensitive spectroscopy cameras.
Adjust half wave plate (HWP1) to set power incident upon objective (and PM2) to ~1 mW.
Using the imaging optics (Figure 10: blue dashed line), check sample image and ensure laser spot is in desired location with no stigmation (optimize with 8.3 if there is).
NOTE: The next 10 steps are used initially to ensure laser is efficiently coupled into spectrometer. Once complete, these steps do not need repeating until a significant change is made in the optical setup.
Adjust sample position as per 8.6 so that laser spot is focused on a clean area of silicon.
Set spectrometer to zeroth order and use observation camera built in to spectrometer (Figure 10 component E) to view image of the input slit on first stage of spectrometer (Slit 1).
Open Slit 1 and check, using the observation camera, that the reflected laser light from the sample is entering slits.
By adjusting coupling lens (L3) ensure center laser spot is on input slits horizontally and on camera vertically.
Repeatedly reduce Slit 1 width and repeat 8.10 to ensure that laser properly centered on Slit 1 and camera. During this process adjust focusing of coupling lens to minimize scatter of laser light from Slit 1 ensuring that reflected laser light is focused approximately at the plane of Slit 1.
Open Slit 1 so that the reflected laser light is not significantly clipped by Slit 1.
Set up spectrometer software, as per manufacturer's protocol, to collect Raman scattering from 520 cm^-1 silicon Raman peak.
Set power to 10 mW.
Take repeated Raman spectra with one second exposures to begin focusing.
Adjust Z-focus of sample until well-defined 520 cm^-1 Si peak is observed.
Maximize this signal by adjusting input half-wave plate (HWP2) (this will depend on the polarization of the outgoing resonance and the gratings in the spectrometer), input lens and Z-focus of sample.

9. Measurement of Single Raman Spectrum

Set desired temperature (4 K) and allow system to equilibrate (~40 min).
Set incident laser power upon PM2 to ~2 mW.
Set wavelength on spectrometer software to that determined in step 8.4.
Set center shift on spectrometer software to 0 cm^-1 and acquire a short (500 msec) Raman spectra to measure laser line.
Use value determined in 9.4 to set new, more precise wavelength in spectrometer software.
Set center shift and spectral window in software to observe predicted Raman modes and so that the spectral window does not encompass the laser line tail.
Move sample position to an area of interest (choice of sample position for bundled tubes is important, see section 14 for further details).
Acquire Raman spectra with CCD focusing on 1 sec exposures as per the manufacturer's protocol.
Adjust the Z-focus position of the sample using stage controllers to maximize the reflected power at the power meter (PM1).
Acquire a Raman spectrum using suitable exposure time to get sufficient signal (>1,000 counts absolute).

10. Measurement of Laser Power Dependence of Raman Cross-section

Set laser wavelength to estimated peak of resonance for specific sample at the working temperature.
Set a low power (~0.1 mW) and acquire Raman spectra as per section 9.3-9.10 of this protocol.
Increase power (by ~0.1 mW), ensuring that as HWP1 is rotated the laser spot on sample does not shift. If the laser spot shifts on rotation of HWP1 then realign as per 8.3 to ensure this does not happen and start experiments again.
Repeat 10.3 for a suitable range of powers to up to ~5 mW. Repeat this process for each working temperature.
Plot the fitted intensity of observed Raman features versus laser power and determine the linear region. Perform all subsequent Resonance Raman experiments at that temperature with 80% of the upper power limit of the linear region.

11. Measurement of Laser Energy Dependence of Raman Cross-section

Set desired excitation wavelength (e.g. 700 nm) and align system accordance with sections 8.1-8.6, setting incident power to that determined from section 10.
Maximize reflected power by adjusting Z-focus of sample and continuously acquire 1 sec exposures in order to check the intensity of the main Raman features.
Set exposure time and accumulations to maximize signal on CCD without saturating detector.
Save spectra noting the in the filename the grating used, exposure time, accumulations, center Raman shift, excitation energy and incident power.
Set next excitation wavelength by repeating steps 8.1-8.6 ensuring the incident laser power is constant and then maximize reflected power as per step 11.2. For initial results use excitation laser wavelengths approximately 10 nm apart. For presentation quality results laser wavelengths separations of approximately 2 nm are preferable.
After each six new excitation wavelengths return to one previous excitation wavelength (e.g. 700 nm) and repeat 11.1-11.5. Plot the fitted intensity of one key Raman feature from the repeated spectra as a function of the experimental time and ensure there is no long-term drift.

12. Measurement of Polarization Dependence of Raman Spectra

Place the polarization analyzer (Pol2) into the path between the objective and the spectrometer as shown in Figure 10 (purple dotted line). Additionally place a half wave plate and polarizer (HWP3 and Pol3) into the optical path prior to the objective; this will be used to rotate the incident polarization. Ensure that all polarizers and HWPs are aligned correctly, so the incident radiation is perpendicular to the optical axis and travels through the center of the optics.
Adjust Pol3 to pass vertically polarized light. Using a strong Raman signal, e.g. a piece of bare silicon, adjust (Pol2) to pass vertical polarized light and adjust HWP2 to maximize intensity of Raman signal. Note the rotation of the HWP2 and the direction of the polarization of the light going into the spectrometer. Ensure that in the rest of the experiment, the polarization of the light incidence on the experiment is unchanged by adjusting HWP2 to compensate any change in the polarization analyzers pass direction.
Check the alignment of the polarization analyzer; rotate the polarizer 180° to make sure the signal is still the same.
Perform step 12.3 with the HWP (rotating it in 90° steps around its full revolution).
Note the change in signal if any at each step.
Maximize the reflected power by adjusting the Z-focus and acquire Raman spectra using appropriate input power and exposure time/accumulations.
Adjust collection polarizer with an appropriate pitch (10°) and adjust HWP in a manner as to maintain the polarization of the light incidence on the spectrometer constant as discussed in 12.2.
Repeat step 12.7 until the full range of the polarizer has been measured.
Change the polarization of the light incident onto the objective to horizontal.
Check that this has not caused the laser spot to move on the sample. Repeat the measurement in steps 12.7 and 12.8. Other incident polarizations may also be used but at least two, perpendicular polarizations are necessary. If using non-horizontal or vertically polarized light the effect of the optics between Pol3 and the objective on the polarization of the light needs to be taken into consideration.
Check the polarization dependence against that expected for ensembles of 1D objects to determine which Raman features are associated with the encapsulated nanowires (see Representative Results).

13. Measurement of Temperature Dependence of Raman Spectrum

Set new sample temperature on cryostat controller in accordance with manufacturer's protocol.
By observing cryostat temperature and the movement of the sample ensure that the cryostat is in thermal equilibrium and there is no sample movement before continuing.
Correct for any thermal drift of sample position by observing the sample in cryostat with and without laser illumination.
Ensure that the laser power is in the linear regime following steps from section 10.
Measure the laser energy dependence of the Raman Cross-section as in section 10. It is common for the optical resonances of the sample to shift with temperature although often the energy of the resonance changes relatively slowly with temperature.

14. Choice of Sample Position

After mounting a sample, find an obvious position on the sample, e.g. a corner, and note the position of the cryostat translations stages, by adding in the components as indicated by the blue dashed line in Figure 10.
Move to another obvious position, e.g. along one of the edges, and note its position.
NOTE: Sample position is important when studying ensembles of filled carbon nanotubes. It is likely that the sample will be inhomogeneous. A good position on the sample has the following characteristics.
Find a location that is visually obvious when viewed through the microscope with detail on micron scale allowing you to return reliably to its position.
Measure Raman signal from sample and adjust XY position slightly to check homogeneity of area on the few micron scale. If signal varies significantly choose a different spot.
Capture an image of the spot and note the relative coordinates from sample corner to be able to return to sample.

15. Post Data Processing

Import the spectra into data handling software.
Normalize each spectrum with respect to laser power and exposure time to obtain counts per sec per mW.
Correct for the spectrometer efficiency.
NOTE: Some spectrometer software does this automatically but, if not, then follow the following procedure. Steps 15.3.1-15.3.2 can be done once for any particular spectrometer and then used as necessary later.
1. Place a calibrated white light source at the position of the sample and measure its spectrum with all standard settings of the spectrometer.
2. Divide the white light spectrum with the calibration curve for the white light source to obtain throughput of the spectrometer. Store the throughput files for later use.
3. Divide the measured Raman spectrum by the throughput of the spectrum under identical conditions.
Plot the Raman spectra using appropriate data handling software.
Check spectra for evidence of the laser jumping between energies during the spectrum. This will produce broader peaks or a doubling up of the peaks in a spectrum.
Check the Raman shift calibration by checking a known Raman feature, e.g. silicon LO (Longitudinal Optical) phonon, or checking for sudden changes in the shift of all of the Raman features in related spectra by the same amount.
Fit Raman features using standard line shapes and a non-linear curving fitting program to obtain amplitude, center shift and width for all features.
Plot the fit parameters versus laser energy or temperature as required.

Representative Results

Representative results for a series HRTEM images and simulations on a sample of HgTe@SWCNTs are displayed in Figure 1. The images throughout Figure 1A–F, depict low dimensional, confined HgTe extreme nanowires, with a diameter of ~1 nm, whose microstructure corresponds to the form discussed in ref¹⁴. Representative images of bundles and discrete tubes are presented in Figure 1D. As per the protocol, a trial model is generated and simulated throughout various tilt angles and beam orientations, representative results of this is indicated in Figure 1A, B, C. These image simulations can be cross-correlated to real experimental results (Figure 1D, F) and can be seen to be a good match with simulations.

The main aim of the experiments described in this paper is to measure Raman spectra from extreme nanowires like those presented in Figure 2. The spectra presented in Figure 2 were measured using a sample of HgTe extreme nanowires taken from the same growth batch as the nanowires present in Figure 1. The sample was prepared for Raman using the method set out in sections 6 and 7 of the protocol. The spectra presented in Figure 2 show a large number of peaks most of which can be attributed to extreme nanowire vibrational excitations and multi-phonon Raman involving overtones and combinations of these vibrational excitations. The fundamental vibrational modes, A (45 cm^-1), B (52 cm^-1), C (94 cm^-1) and D (115 cm^-1), and some of their combinations and overtones are labeled on the spectra visible up to at least 6^th order. The detailed attribution and interpretation of the HgTe Raman spectra are set out in reference¹⁴. It should be noted that strong multiple phonon Raman is a common feature of II-IV materials, such as HgTe, and not necessarily a feature of all extreme nanowire samples. In addition to the nanowire features the Raman spectra also contain one carbon nanotube Raman feature; predominantly due to a Radial Breathing Mode observed at 168 cm^-1 whose resonant energy of 1.67 eV¹⁴ is clearly different from the resonance energies of the filling Raman features (Figure 4). The host tube Raman features can be clearly identified from Raman spectra of the pure nanotubes used for filling. A resonance Raman investigation of the unfilled tubes with a broader range of excitation energies is shown in the supplementary material along with an initial attribution of the 5 RBMs identified in this data.

The data presented in Figure 2 demonstrates the strong excitation laser energy dependence that is common in 1D system. This energy dependence is one of the key indicators that any Raman features observed are due to extreme nanowires rather than other forms of the parent material, or its thermal decomposition products, which remain in the sample after cleaning. Another key indicator is that the observed features are quite different from those of bulk HgTe³⁰ which are dominated by a Longitudinal Optical (LO) phonon mode at 137 cm^-1. There is significant evidence in the literature that Raman spectra of nanoparticles of HgTe with diameters down to 3 nm are dominated by bulk LO phonon derived vibrational modes and the same is true of HgTe quantum wells with dimensions down to 2 nm. The final key indicator that specific Raman features are associated with nanowires rather than nanoparticles or lumps of the parent material is a characteristic polarization dependence like that shown in Figure 3. As discussed in more detail in reference¹⁴ the Raman scattering from an ensemble of randomly oriented 1D systems is preferentially polarized in the same direction as the exciting laser light with a contrast ratio of 3:1 and thus shows the characteristic figure of eight shape present in the optimum results shown in Figure 3. It is important to test that preferred emission direction rotates with the excitation polarization, as shown in Figure 3, as polarized Raman due to other mechanisms is not uncommon. It is quite possible to observe a contrast ratio lower than 3:1 for thick layers of nanowires, as also shown in Figure 3, and this can be attributed to scattering of light within the layer.

Another possible explanation of Raman peaks in filled tube samples that are not present in unfilled tubes and not due to residual filling is that filling or residual material leads to modifications of the SWCNT Raman spectrum. For instance samples of SWCNTs which have had metal evaporated onto them exhibit "Squash" vibrational modes.^31,32 However in the case of the HgTe filled samples we observe the opposite polarization dependence (Figure 3) to that observed for Squash modes.³¹ In addition the fact that high harmonics of the fundamental modes are observed in HgTe spectra and not for the Squash mode spectra allows us to rule out a Squash mode explanation for the HgTe Raman features.

The excitation photon energy dependence of the intensity of the B Raman feature taken from a full Resonance Raman experiment using the protocol set out in this paper is presented in Figure 4. Also presented is the same result from an experiment performed before the protocol was fully developed. With the protocol it is possible to get a variation in repeated, independent measurements of a single point on the resonance profile of approximately 8% as shown in Figure 5. The main parts of the alignment of the system that need to be controlled in order to get good quality spectra are alignment of the laser beam into the microscope objective and then focusing of the beam onto the sample. The importance of beam alignment is illustrated in Figure 6a, e. In this figure Raman spectra are shown (Figure 6a, blue trace) with the beam correctly aligned onto the two beam steering cameras (c and e) and sub-optimal spectra (Figure 6a, green trace) with the beam deliberately misaligned. A line through the vertical and horizontal center point of each of the frame b, e de Figure 6 shows there is small horizontal drift in the laser alignment as illustrated when 6b and 6d are compared. Comparing the green and blue traces in 6a, it is clear that a small misalignment can lead to significant variation (>50% loss) of Raman signal hitting the CCD.

The importance, and relevance, of using the reflected beam intensity to ensure the objective is correctly focused on the sample is illustrated in Figure 7. This figure presents the Raman intensity and reflected light signal as a function of the distance between the objective and the sample. To be within 10% of the peak Raman, the precision of the Z-position (the distance between the objective and sample) needs to be better than 20 µm, which is considerably larger than the distance between the peak positions of power and Raman as presented in Figure 7.

As discussed in the protocol it is important that the effect of laser excitation intensity on the Raman spectra are taken into account and that the experiment be in the regime in which the Raman scattering is proportional to the excitation intensity when measuring resonance profiles. Representative measurements of the excitation intensity dependence of the Raman scattering intensity of HgTe extreme nanowires, measured as per section 9 of the protocol, is shown in Figure 8. As presented in Figure 8 the Raman intensity initially increases linearly with excitation intensity up to an intensity of 1.5 x 10⁴ before starting to show non-linear behavior with a tendency for the signal to saturate. The precise excitation intensity behavior of different samples will differ and so must be measured and taken into account. From Figure 8 the Raman intensity is clearly within the non-linear regime for excitation intensities greater than ~0.2 mW/mm². Also shown is a linear fit to the data at low excitation intensities demonstrating that at sufficiently low enough excitation intensities the Raman intensity is proportional to excitation intensity (up to ~0.1 mW/mm²). It is important to reiterate this data is unique for this particular sample position at a particular temperature (4 K) and the experiment must be repeated as per the protocol steps when a different sample/temperature is investigated. As a general rule of thumb, it is ideal to use about 80% of the maximum power in the linear regime.

Once high quality Resonance energy dependence profiles have been measured these can then be analyzed to obtain a range of information. The theory underlying Raman processes is well understood and time dependent perturbation theory¹⁷, often calculated using a Feynman diagram approach^21,33, can be used to predict resonance profiles and even absolute intensities. In the limit that the optical transitions are discrete and well separated in energy the theory predicts that the Raman intensity for single phonon scattering follows a Lorentzian lineshape centered at the optical transition multiplied by one centered one phonon energy above for Stokes scattering or one phonon energy below for Anti-Stokes Raman scattering. If the energy of the phonon is small compared to the resonance linewidth, as is the case for HgTe nanowires, this will lead to the Resonance having a Lorentzian squared lineshape. However in 1D systems it is likely that the features in the optical spectrum will be associated with van Hove singularities consisting of a continuum of states. In addition there is likely to be inhomogeneity within the sample further broadening the transition. If either or both of these are true then the density of states for the optical transitions will alter and can dominate the lineshape. The situation is made more complex because Raman scattering is a coherent process and so interference effects involving different scattering sequences and different intermediate states will alter the resonance profile³⁴. For the same reason any variation of coherent lifetime amongst the intermediate states can also affect the lineshape³⁵. The possibility of the involvement of elastic scattering from defects and double resonance effects, particularly in higher order Raman scattering, further complicates the situation^21,35. It is often therefore not possible to a priori predict the expected Raman resonance profile. However resonance Raman scattering has been used to extract a great deal of information about different materials systems including the energy of features in the optical spectrum, the nature of the state's responsible for those features and the nature and quantitative strength of electron-phonon interactions¹⁷. In order to better quantify the energy and energetic width of the optical features within the Resonance profile it is often helpful to fit them using one of the standard optical lineshapes. In the case of the HgTe nanowires we tried Lorentzian, Lorentzian squared and Gaussian lineshapes and found the Gaussian lineshapes to be the best fit (Figure 4). To be clear this is a phenomenological fit and the use of the Gaussian lineshape cannot be interpreted in terms of the nature of the broadening of the optical feature which is causing the resonance. From these fits we can determine the energy of the optical feature responsible for the resonance to be 1.76 eV. A more detailed analysis of the resonance behavior of HgTe extreme nanowires will be published separately.

The measurement of the temperature dependence of Raman spectra enables additional physics to be probed. In particular the shift of the vibrational energies and the width of vibrational peaks allows for anharmonic effects, leading to lattice dilation and fundamental limits on the lifetime of phonons to be investigated. Measurements of Resonance profiles as a function of temperature will allow the temperature dependence of optical energies to be determined. Some representative results illustrating possible temperature related effects are presented in Figure 9. It can be seen from Figure 9 (a and b) that as temperature increases the spectral width broadens and the center shift of the mode softens, which is in-line with theoretical predictions. The most striking is window c, indicating a dramatic drop-off in intensity of the B mode as a function of temperature. This effect, which will be discussed in more detail in a separate publication, is predominantly due to a decrease in the coherent lifetime of the optical states responsible for the resonance with increasing temperature and is clear evidence that Raman scattering can provide information far beyond that possible with absorption measurements.

In order for the intensity of Raman scattering at different temperatures to be directly compared, drift of the lateral position of the sample needs to be corrected for. The inclusion of a light source and camera to allow the sample to be viewed through the microscope objective allows for the repositioning of the sample. If a "good" sample position is chosen as per step 14 of the protocol then it is possible to reposition the sample and achieve a reproducibility of the intensity of the Raman peak of better than 8% as shown in Figure 5.

Figure 1: HRTEM of extreme nanowires with comparison to simulation results. Structure models, HRTEM simulation protocol and experimental images of ~1 nm thick HgTe nanowires embedded in ~1.4 nm diameter SWNTs. A typical partial cutaway model (a) of a 3 nm long fragment of HgTe embedded in a (10,10) SWNT. Electron beam directions (b) represent different projections for a series of orientations of the HgTe@(10,10)SWNT composite (c, LH simulations) and tilt (d, RH simulation). HRTEM images (e, top right) can be matched against the table (c) and matched with the experimental image (d top left and right). HRTEM image obtained from a thin SWNT bundle (e), used to observe embedded ~1 nm HgTe nanowires (I, II and III) and correlated with simulations in the tableau (i.e. insets I', II', and III'). Some fragments are tilted (f, left) by angle t, modeled by simulation (f, middle) that corresponds to the cutaway model as in f right. Please click here to view a larger version of this figure.

Figure 2: Raman spectra of extreme Mercury Telluride embedded within nanotubes. Representative Raman spectra of HgTe extreme nanowires in SWCNTs acquired at 4 K with multiple excitation photon energies. The various traces correspond to excitation energies of 1.78, 1.77, 1.75 and 1.71 eV for the blue, green red and purple lines respectively. Please click here to view a larger version of this figure.

Figure 3: Fitted intensity of B peak as a function of analyzer angle. Polar plot of fitted intensity of the B peak at 1.77 eV and 4 K as a function of analyzer angle at vertical (blue) and horizontal (green) incident polarization. Please click here to view a larger version of this figure.

Figure 4: Resonance effects observed in B mode of HgTe@SWCNTs. Resonance profile of B (52 cm^-1) mode as a function of laser wavelength for both (a) the case where the protocol detailed is adhered to and the case (b) taken before the protocol was developed. The Gaussian line widths are centered around 1.77 ± 1 meV and 1.74 ± 3 meV for a and b respectively. The errors were determined by the 95% confidence bounds of the fitting routine. Please click here to view a larger version of this figure.

Figure 5: Independent repeats of Raman spectra at 702 nm incident wavelength throughout RRS experiment. A series of Raman spectra, taken under identical conditions throughout the experiment. The spectra show the A and B mode measured with a 702 nm laser line at 4 K during a resonance Raman experiment. Please click here to view a larger version of this figure.

Figure 6: Raman spectra of HgTe@SWCNTs taken when system is optimized and deliberately de-tuned. Raman spectra acquired at room temperature when the system is well aligned (blue trace) and deliberately misaligned (green trace). Frames (b, d) show laser image on camera (C2) and (c, e) show laser spot on camera (C1). The well-aligned spectra correspond to the images from b and c whilst the deliberately misaligned spectra are shown through d and e. Please click here to view a larger version of this figure.

Figure 7: Reflected power and corresponding Raman peak intensity of Si peak as a function of sample focal-position. Plot of the normalized reflected power (red) measured on power meter (PM2) and the normalized intensity of Raman intensity (blue) as a function of distance between sample and objective. Please click here to view a larger version of this figure.

Figure 8: Plot of the intensity of the B Raman mode at 4 K and 702 nm quantified with Lorentzian fitting as a function of excitation intensity. The fitted intensity of the B mode as a function of incident power, where a fit is applied to determine the linear regime. Please click here to view a larger version of this figure.

Figure 9: Temperature dependence of B mode in HgTe@SWCNTs at fixed (1.77 eV) excitation energy. Raman spectra acquired at constant excitation energy (1.77 eV) as a function of temperature. Windows a-c shows the spectral width, center shift and fitted intensity of the B modes respectively. Error bars shown are the 95% confidence bounds from the fitting routine. Please click here to view a larger version of this figure.

Figure 10: Schematic of optical setup employed for resonance Raman Spectroscopy experiments. Figure displays optical setup employed for all experiments discussed in protocol. Please click here to view a larger version of this figure.

Discussion

Whilst a huge amount of research has been done on nanowires the fundamental limit of the smallest diameter nanowires possible, extreme nanowires, has hardly been explored. It has already been shown that the properties of these nanowires do not form a continuum with even slightly larger diameter nanowires; e.g. they can exhibit entirely new crystalline forms of their parent materials. Considering the large number of possible parent materials and that each parent can produce many more than one extreme nanowire the range of possible nanowires physics is huge.

The fact that extreme nanowire research is still in its early stages is not because the methods of producing them are not well established. The melt infiltration process set out in this paper is reliable and has been used by many groups and other approaches such as sublimation filling are available if melt infiltration is not optimal for any particular filling. In part the field is held back by the lack of a relatively simple and widely applicable method for non-destructively characterizing extreme nanowires. If the field of carbon nanotubes is any guide, Raman spectroscopy has a good chance of being the method of choice for solving this problem. The key to obtaining useful Raman spectra on extreme nanowires is to recognize that in common with all other 1D systems resonant enhancement of the Raman scattering is a necessary condition for observing any scattering. Once the full resonance behavior of a particular sample type has been determined using the methods set out in this protocol it is possible to use a fixed resonant excitation energy for most applications of Raman to characterizing the sample that will speed up the measurements and reduce the cost of the Raman system required.

As shown in the results presented in this paper the critical problem in obtaining high quality Resonance Raman results on extreme nanowires is the need to be able to reproducibly realign the beam of a tunable laser over several days with high precision. This requires particular modifications to the experimental system and attention to the most important details of the experiment; correct focusing of the optical system, precise alignment of the laser beam onto the microscope objective and the ability to correct precisely for any lateral movement of the sample. The techniques developed to achieve this form the basis of this paper. Others have developed techniques and systems for improving the reproducibility of resonant Raman experiments including pioneers such as M. Cardona who applied the technique to a wide range of bulk and quantum well systems. Our technique also builds upon the work of the pioneers of Raman in carbon nanotubes including M. Dresselhaus²¹. However the protocol presented here is particularly suitable for Resonance Raman experiments on extreme nanowires.

A key part of the success of the protocol was the development of the experimental system shown in Figure 10. The figure demonstrates a plan view of the optical setup employed for the Raman experiments detailed in the protocol. Laser light is focused through a 50X objective (labeled OB) upon the sample, sealed in the cryostat as per the protocol. This cryostat is mounted on an XYZ stage to allow 3 dimensional movement of the sample for purposes of repositioning and focusing. Laser light is generated through A and B (being a pump source and Ti:sapphire respectively), exact details of the laser being noted in the materials document provided. When using the commercial laser line filter (component C) laser light is directed through the center of iris 1 and 2 and collimated using lens 1 and 2 (L1 and L2). The light passes through a half-wave plate and polarizer (HWP1 and Pol1) to control plane of polarization and laser power incident upon PM2, as detailed in the protocol. Laser light is passed through the tunable filter, C, and using mirrors M1 and M2, steered onto the correct optical path such that it is normal to the back face of the objective (OB) and centered on the cameras C1 and C2. The ND filter is used to position the back-reflected beam from the objective onto power meter, PM1, to allow the focusing procedure (step 9.9) to be performed. Back scattered light from the sample is collected and passed through lens 3 (L3) and Slit 1 into the spectrometer. Adjusting the slit width and position of the lens is important to maximize the Raman signal, as detailed in protocol section 8. If the laser wavelength is out of the laser line filters operational range, the Volume Bragg setup needs to be employed as per section 8.2.1-8.2.3. It is important that the optical set up is changed in accordance with the black dashed line as per Figure 10, and the mirror M3 is removed from the path. Finally, if undertaking polarization dependent experiments, it is important to control the polarization and maintain the polarization entering the spectrometer, this is explained in section 12 of the protocol and components to be added to the setup are highlighted by a purple dashed line in Figure 10. The blue dashed line in Figure 10 indicated components that are added to allow live imaging of the sample as indicated by section 14 of the protocol.

As with all experimental methods Resonant Raman scattering has its limitations. In particular, the available tunable laser sources and detectors mean that it is much easier to perform in the spectral range 350-1,000 nm although extension further into the infrared and UV are possible. The experimental system required to undertake Raman scattering with tunable sources is not cheap with a reasonable estimate being £200-300k at the time of publication. In addition the complexity of the systems required means that they require some familiarity with optical spectroscopy to operate successfully. However Raman scattering provides a combination of information that is hard to obtain from other techniques. Remarkably it is possible to obtain Raman scattering, and thus vibrational energies, from individual single walled carbon nanotubes that cannot yet be achieved by any other technique.

Now that the resonances of nanowires are starting to be determined this opens up a range of possible extensions of Raman scattering. In our opinion the extension to electrochemically gated extreme nanowires²⁰ at temperatures down to 4 K³⁶, allowing measurements on nanowires over a wide range of charge densities will be key to understanding these materials. Finally using Raman scattering to understanding structural and melting transitions of extreme nanowires may help to optimize the quality of the samples that can be produced even further.

Divulgaciones

The authors have nothing to disclose.

Acknowledgements

The authors acknowledge financial support from the Engineering and Physical Sciences Research Council, UK under the Program Grant ‘Supercritical Fluid Electrodeposition’ (EP/J016276/1). J.S. and R.J.K. are indebted to the Warwick Centre for Analytical Science (EPSRC funded Grant EP/F034210/1). Additionally, we are indebted to Drs. Zheng Liu and Kazu Suenaga who provided the top right part of Panel d of Figure 1, which originally appeared in Microsc. Semicond. Mater. 2008, 120, 213-216 (used with permission).

Materials

Carbon Nanotubes	Nanointegris	NI96
Carbon Nanotubes	Private		Synthesis described in Eurasian Chem.-Technol. J. 2005, 5, 7-18.
Mercury Telluride	VMR		99.999% metals basis
Silica Quartz Tubing	H. Baumbach & Co.		Various diameters and lengths used – typically 1 cm OD, 0.8 cm ID and 8cm long.
Tube furnace	Carbolite	MTF-12/38/250
JEOL ARM 200F	JEOL		200 kV High Resolution TEM Operated at 80 kV and equipped with
			CEOS hardware spherical aberation (Cs) imaging corrector. Cs corrected
			to 0.001 mm.
SC1000 ORIUS camera	Gatan		Size of CCD 4008 x 2672
Digital Micrograph Suite 2.31	Gatan		64 bit version
XMax X-ray Microanalysis	Oxford Instruments		This detector uses the silicon drift detection (SDD) principle. 1 nm diameter electron probe.

Crystalmaker Ver 8.7	Crystalmaker		Used for assembling crystal fragments for image simulations
Nanotube Modeler	JCrystalSoft ©2015-2015		Used for generating Nanotube models
SimulaTEM	Private		Ultramicroscopy, 2010, 110, 95-104.

Verdi V8 Pump	Coherent
Mira 900 Ti:Sapphire	Coherent
Volume Bragg Grating	Optigrate		Specfication between 680-720nm
Photonetc TLS 850 LLTF	Photonetc		Tunable between 700-1000nm
LMPLAN IR50x MircoscopeObjective	Olympus
Cryostat	Oxford Instruments
Triple Raman Spectrometers	Princeton Instruments		triple 600nm using gratings 900, 900, 1800 lines/mm
CCD	Princeton Instruments		deep depleted, UV enchanced liquid N2 Cooled Silicon CCD

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Smith, D. C., Spencer, J. H., Sloan, J., McDonnell, L. P., Trewhitt, H., Kashtiban, R. J., Faulques, E. Resonance Raman Spectroscopy of Extreme Nanowires and Other 1D Systems. J. Vis. Exp. (110), e53434, doi:10.3791/53434 (2016).