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وتوليف [القصدير<sub> 10</sub> (سي (سايم<sub> 3</sub>)<sub> 3</sub>)<sub> 4</sub>]<sup> 2</sup<sup> -</sup> باستخدام متبدل الاستقرار القصدير (I) الحل هالايد تجميعي عبر تقنية المشارك التكثيف
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化学
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JoVE 杂志 化学
The Synthesis of [Sn10(Si(SiMe3)3)4]2 Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
DOI:

12:43 min

November 28, 2016

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Chapters

  • 00:05Title
  • 01:14Setup of the Graphite Reactor and Co-condensation Apparatus
  • 04:48Co-condensation Reaction
  • 08:59Synthesis of Sn10(Hyp)42-
  • 09:57Results: Metastable Sn(I) Chloride Solution Obtained by Co-condensation Applied for Preparation of [Sn10(Si(SiMe3)3)4]2-
  • 10:51Conclusion

Summary

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The disproportionation reaction of a metastable Sn(I) chloride solution, obtained via the preparative co-condensation technique, is used for the synthesis of a metalloid tin cluster compound.

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